Ethyl 3,5-bis[(tert-butoxycarbonyl)oxy]benzoate

Base Information

Chemical Name:Ethyl 3,5-bis[(tert-butoxycarbonyl)oxy]benzoate
CAS No.:918402-90-1
Molecular Formula:C19H26O8
Molecular Weight:382.411
Hs Code.:
DSSTox Substance ID:DTXSID00575607
Nikkaji Number:J2.404.139E
Wikidata:Q82465010

Synonyms:918402-90-1;Ethyl 3,5-bis[(tert-butoxycarbonyl)oxy]benzoate;DTXSID00575607

Suppliers and Price of Ethyl 3,5-bis[(tert-butoxycarbonyl)oxy]benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ethyl 3,5-bis[(tert-butoxycarbonyl)oxy]benzoate

Chemical Property:

PSA：97.36000
LogP:4.49110
XLogP3:4.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:11
Exact Mass:382.16276778
Heavy Atom Count:27
Complexity:491

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1=CC(=CC(=C1)OC(=O)OC(C)(C)C)OC(=O)OC(C)(C)C

Technology Process of Ethyl 3,5-bis[(tert-butoxycarbonyl)oxy]benzoate

There total 1 articles about Ethyl 3,5-bis[(tert-butoxycarbonyl)oxy]benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 24424-99-5
di-tert-butyl dicarbonate

: 4142-98-7
ethyl 3,5-dihydroxybenzoate

: 918402-90-1
3,5-bis-tert-butoxycarbonyloxy-benzoic acid ethyl ester

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1021/ol0625536

Reference yield: 93.0%

: 918402-90-1
3,5-bis-tert-butoxycarbonyloxy-benzoic acid ethyl ester

: 98-88-4
benzoyl chloride

: 2-benzoyl-3,5-bis-tert-butoxycarbonyloxy-benzoic acid ethyl ester

Guidance literature:: 3,5-bis-tert-butoxycarbonyloxy-benzoic acid ethyl ester; With tetramethylpiperidyl MgCl LiCl; In tetrahydrofuran; at 0 ℃; for 3h;

In tetrahydrofuran; at -40 ℃; for 0.0833333h;

benzoyl chloride; In tetrahydrofuran; at -40 - 20 ℃;
DOI:10.1021/ol0625536

Reference yield: 90.0%

: 918402-90-1
3,5-bis-tert-butoxycarbonyloxy-benzoic acid ethyl ester

: 100-52-7
benzaldehyde

: carbonic acid 7-tert-butoxycarbonyloxy-3-oxo-1-phenyl-1,3-dihydro-isobenzofuran-5-yl ester tert-butyl ester

Guidance literature:: 3,5-bis-tert-butoxycarbonyloxy-benzoic acid ethyl ester; With tetramethylpiperidyl MgCl LiCl; In tetrahydrofuran; at 0 ℃; for 3h;

benzaldehyde; In tetrahydrofuran; at -40 ℃; for 3h;
DOI:10.1021/ol0625536