inositol 2-monophosphate

Base Information

• Chemical Name: inositol 2-monophosphate
• CAS No.: 7336-80-3
• Molecular Formula: C₆H₁₃O₉P
• Molecular Weight: 260.138
• Mol file: 7336-80-3.mol

Synonyms:

Chemical Property of inositol 2-monophosphate

Chemical Property:

• Vapor Pressure: 7.17E-13mmHg at 25°C
• Boiling Point: 517.4°Cat760mmHg
• Flash Point: 266.7°C
• PSA: 177.72000
• Density: 2.02g/cm³
• LogP: -3.71760

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of inositol 2-monophosphate

There total 35 articles about inositol 2-monophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,4,5-tri-O-acetyl-3,6-di-O-benzyl-2-O-(3-oxo-1,5-dihydro-3λ5-2,4,3-benzodioxaphosphepin-3-yl)-D-myo-inositol (864372-89-4) → myo-Inositol 2-phosphate (573-35-3,633-88-5,2831-74-5,4956-00-7,7336-80-3,13004-72-3,13331-65-2,15421-51-9,21667-10-7,26277-10-1,26545-79-9,34218-99-0,34219-00-6,34219-01-7,35275-50-4,46495-37-8,46495-38-9,46495-39-0,57652-30-9,69256-52-6,84414-08-4,111901-84-9)

Guidance literature:

1,4,5-tri-O-acetyl-3,6-di-O-benzyl-2-O-(3-oxo-1,5-dihydro-3λ⁵-2,4,3-benzodioxaphosphepin-3-yl)-D-myo-inositol; With hydrogen; palladium on activated charcoal; In ethanol; water; at 20 ℃;

With sodium hydroxide; water; for 4h; cooling;

DOI:10.1002/ejoc.200400911

Reference yield: 60.0%

C39H47O9P → (+/-) myo-inositol 4-phosphate (573-35-3,633-88-5,2831-74-5,4956-00-7,7336-80-3,13004-72-3,13331-65-2,15421-51-9,21667-10-7,26277-10-1,26545-79-9,34218-99-0,34219-00-6,34219-01-7,35275-50-4,46495-37-8,46495-38-9,46495-39-0,57652-30-9,69256-52-6,84414-08-4,111901-84-9)

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethanol; water; at 25 ℃; under 2585.7 Torr;

DOI:10.1039/c39870000314

Reference yield:

[3H]-Phytic acid → D-myo-inositol (87-89-8) + myo-Inositol 2-phosphate (573-35-3,633-88-5,2831-74-5,4956-00-7,7336-80-3,13004-72-3,13331-65-2,15421-51-9,21667-10-7,26277-10-1,26545-79-9,34218-99-0,34219-00-6,34219-01-7,35275-50-4,46495-37-8,46495-38-9,46495-39-0,57652-30-9,69256-52-6,84414-08-4,111901-84-9) + Phosphoric acid mono-((1R,2S,3S,4S,5R,6S)-2,3,6-trihydroxy-4,5-bis-phosphonooxy-cyclohexyl) ester + Phosphoric acid mono-((1S,2R,3R,4R,5R,6R)-2,3-dihydroxy-4,5,6-tris-phosphonooxy-cyclohexyl) ester

Guidance literature:

With phytase from wheat bran of T_. aestivum L_. cv. Nourin No_. 61; water; In acetate buffer; at 37 ℃; pH=5.5; Product distribution;

DOI:10.1271/bbb.64.995

upstream raw materials:

2-O-phosphono-1,3,4,5,6-penta-O-acetyl-myo-inositol

D-myo-inositol

3,3,7,7-tetramethyl-2,8-dioxa-5-aza-1λ³-phosphabicyclo(3,3,0)octane

4,6-di-O-benzyl-myo-inositol 2-dibenzylphosphate

Downstream raw materials:

inositol

phosphoric acid

DL-O¹,O²-hydroxyphosphoryl-myo-inositol

Refernces

• 1、 Greiner, Ralf,Larsson Alminger, Marie,Carlsson, Nils-gunnar,Muzquiz, Mercedes,Burbano, Carmen,Cuadrado, Carmen,Pedrosa, Mercedes M.,Goyoaga, Carmen. "Pathway of dephosphorylation of myo-inositol hexakisphosphate by phytases of legume seeds". . p. 6865 - 6870. Retrieved 2007/10/03.
• 2、 Schmitt, Laurent,Bortmann, Patrick,Schlewer, Gilbert,Spiess, B.. "myo-Inositol 1,4,5-Triphosphate and Related Compounds' Protonation Sequence: Potentiometric and 31P NMR Studies". . p. 2257 - 2264. Retrieved 2007/10/02.