DIETHYL-THIOCARBAMIC ACID S-BUTYL ESTER

Base Information

• Chemical Name: DIETHYL-THIOCARBAMIC ACID S-BUTYL ESTER
• CAS No.: 91852-97-0
• Molecular Formula: C₉H₁₉NOS
• Molecular Weight: 189.322
• Mol file: 91852-97-0.mol

Synonyms:Carbamicacid, diethylthio-, S-butyl ester (6CI)

Chemical Property of DIETHYL-THIOCARBAMIC ACID S-BUTYL ESTER

Chemical Property:

• Vapor Pressure: 0.118mmHg at 25°C
• Boiling Point: 219.6°Cat760mmHg
• Flash Point: 86.6°C
• PSA: 45.61000
• Density: 0.965g/cm³
• LogP: 2.98150

Purity/Quality:

99% ^*data from raw suppliers

DIETHYL-THIOCARBAMIC ACID S-BUTYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DIETHYL-THIOCARBAMIC ACID S-BUTYL ESTER

There total 7 articles about DIETHYL-THIOCARBAMIC ACID S-BUTYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

dibutyl disulfide (629-45-8) + carbon monoxide (201230-82-2) + diethylamine (109-89-7) → S-Butyl N,N-diethylthiocarbamate (91852-97-0)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 120 ℃; for 48h; under 38000 Torr;

DOI:10.1021/jo048350h

Reference yield: 43.0%

S-butyl-N,N-diethyl-thiohydroxylamine (23870-65-7) + carbon monoxide (201230-82-2) → S-Butyl N,N-diethylthiocarbamate (91852-97-0)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In pyridine; at 100 ℃; for 20h; under 14701.2 Torr;

DOI:10.1021/jo9823137

Reference yield:

N,N-diethylcarbamyl chloride (88-10-8) → S-Butyl N,N-diethylthiocarbamate (91852-97-0)

Guidance literature:

With xylene;

DOI:10.1021/ja01512a052

upstream raw materials:

butyl chlorothioformate

diethylamine

1-iodo-butane

diethylamonium N,N'-dimethylmonothiocarbamate