2-Naphthalenol, 6-(1-methylethyl)-

Base Information

• Chemical Name: 2-Naphthalenol, 6-(1-methylethyl)-
• CAS No.: 91909-30-7
• Molecular Formula: C13H14O
• Molecular Weight: 186.254
• DSSTox Substance ID: DTXSID50440311
• Nikkaji Number: J2.015.560D
• Wikidata: Q82256588
• Mol file: 91909-30-7.mol

Synonyms:2-Naphthalenol, 6-(1-methylethyl)-;6-Isopropyl-2-naphthol;SCHEMBL487450;2-hydroxy-6-isopropylnaphthalene;DTXSID50440311;MDWFMRLBXKFHHI-UHFFFAOYSA-N;2-hydroxy-6-(1-methylethyl)naphthalene;91909-30-7

Chemical Property of 2-Naphthalenol, 6-(1-methylethyl)-

Chemical Property:

• XLogP3: 3.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 186.104465066
• Heavy Atom Count: 14
• Complexity: 188

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)C1=CC2=C(C=C1)C=C(C=C2)O

Technology Process of 2-Naphthalenol, 6-(1-methylethyl)-

There total 2 articles about 2-Naphthalenol, 6-(1-methylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

2,6-diisopropylnaphthalene (24157-81-1) → 2.6-dihydroxynaphthalene (581-43-1) + 2-hydroxy-6-(1-methylethyl)naphthalene (91909-30-7)

Guidance literature:

2,6-diisopropylnaphthalene; With N-hydroxyphthalimide; azobisisobutyronitrile; oxygen; In acetonitrile; at 75 ℃; for 21h; under 15201 Torr;

With sulfuric acid; In acetonitrile; at 25 ℃; for 2h; Further stages.;

DOI:10.1002/adsc.200303168

Reference yield: 20.0%

2,6-diisopropylnaphthalene (24157-81-1) → 2-hydroxy-6-(1-methylethyl)naphthalene (91909-30-7) + 2-(2-hydroxy-2-methylethyl)-6-(2-methylethyl)naphthalene (83922-21-8) + 2-isopropenyl-6-isopropyl-naphthalene

Guidance literature:

2,6-diisopropylnaphthalene; With N-hydroxyphthalimide; oxygen; cobalt(II) acetate; In acetonitrile; at 75 ℃; for 21h; under 760.051 Torr;

With sulfuric acid; In acetonitrile; at 25 ℃; for 2h; Further stages.;

DOI:10.1002/adsc.200303168

Reference yield: 86.0%

para-bromotoluene (106-38-7) + 2-hydroxy-6-(1-methylethyl)naphthalene (91909-30-7) → 2-isopropyl-6-(p-tolyl)naphthalene

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; magnesium; 1,3-di-tert-butylimidazol-2-ylidene; In tetrahydrofuran; toluene; at 25 - 100 ℃; for 36.5h; Inert atmosphere; Schlenk technique; Green chemistry;

DOI:10.1021/acs.orglett.6b02656

upstream raw materials:

2,6-diisopropylnaphthalene

Downstream raw materials:

2-methoxy-6-(1-methylethyl)naphthalene

6-methoxy-2-acetylnaphthalene

2-methoxy-6-(1-hydroxy-1-methylethyl)naphthalene

(rac)‐6,6'‐diisopropyl‐[1,1'‐binaphthalene]‐2,2'‐diol