Chromium, (aminophenylmethylene)pentacarbonyl-, (OC-6-21)-

Base Information

Chemical Name:Chromium, (aminophenylmethylene)pentacarbonyl-, (OC-6-21)-
CAS No.:32370-44-8
Molecular Formula:C₁₂H₇CrNO₅
Molecular Weight:297.187
Hs Code.:
Mol file:32370-44-8.mol

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Chromium, (aminophenylmethylene)pentacarbonyl-, (OC-6-21)-

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of Chromium, (aminophenylmethylene)pentacarbonyl-, (OC-6-21)-

There total 3 articles about Chromium, (aminophenylmethylene)pentacarbonyl-, (OC-6-21)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 27436-93-7
pentacarbonyl(1-methoxybenzylidene)chromium⁽⁰⁾

: 32370-44-8
(aminobenzylidene)pentacarbonylchromium⁽⁰⁾

Guidance literature:: With ammonia;

Reference yield: 66.0%

: 15975-93-6
pentacarbonyl((methyl)((tetramethylammonio)oxy)carbene)chromium⁽⁰⁾

: 506-96-7
Acetyl bromide

: 621-84-1
O-benzyl carbamate

: 121809-09-4
{(N-carbobenzoxyamino)methylcarbene}pentacarbonylchromium⁽⁰⁾

: 32370-44-8
(aminobenzylidene)pentacarbonylchromium⁽⁰⁾

Guidance literature:: In methanol; dichloromethane; in a airlessware flask, under Ar, addn. of AcBr to the soln. of (CH3)4NO(CH3)CCr(CO)5 at - 40 ° C, stirring 1 h, addn. of a soln. of O-benzyl carbamate, stirring 6 h at -40 °C, warming to -15 °C, 22 h at this temp.; filtration (through Celite), chromy.(silica gel column, eluent a) hexane, then 7:1 hexane/Et-acetate), evapn., elem. anal.;
DOI:10.1021/om00111a015

Reference yield: 65.0%

: 121809-06-1
{(O-acetyl ethanimidato)phenylcarbene}pentacarbonylchromium⁽⁰⁾

: 124-41-4
sodium methylate

: 121809-08-3
{(N-acethylamino)phenylmethylene}pentacarbonylchrominm

: 32370-44-8
(aminobenzylidene)pentacarbonylchromium⁽⁰⁾

Guidance literature:: In methanol; diethyl ether; addn. a soln. of MeONa in MeOH to a solnn of 2a in ether, 0.5 h; evapn. (to dryness in vac.), identification of the two products by TLC, isolation by radial chromy. (2-mm silica gel, 30% EtAc/hexane, elem. anal.;
DOI:10.1021/om00111a015