Diazenecarboxylic acid, (4-nitrophenyl)-, 1,1-dimethylethyl ester

Base Information

• Chemical Name: Diazenecarboxylic acid, (4-nitrophenyl)-, 1,1-dimethylethyl ester
• CAS No.: 92722-14-0
• Molecular Formula: C11H13N3O4
• Molecular Weight: 251.242
• Mol file: 92722-14-0.mol

Synonyms:

Chemical Property of Diazenecarboxylic acid, (4-nitrophenyl)-, 1,1-dimethylethyl ester

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diazenecarboxylic acid, (4-nitrophenyl)-, 1,1-dimethylethyl ester

There total 10 articles about Diazenecarboxylic acid, (4-nitrophenyl)-, 1,1-dimethylethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tert-butyl 2-(4-nitrophenyl)hydrazine-1-carboxylate (92491-67-3) → tert-butyl 2-(4-nitrophenyl)diazenecarboxylate (92722-14-0)

Guidance literature:

With manganese(IV) oxide; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1021/jo202406k

Reference yield: 78.0%

tert-butyl 2-(4-cyanophenyl)diazene-1-carboxylate (1354828-66-2) → tert-butyl 2-(4-nitrophenyl)diazenecarboxylate (92722-14-0)

Guidance literature:

With manganese(IV) oxide; In dichloromethane; Inert atmosphere;

DOI:10.1021/jo202406k

Reference yield:

di-tert-butyl dicarbonate (24424-99-5) → tert-butyl 2-(4-nitrophenyl)diazenecarboxylate (92722-14-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 85 percent / acetonitrile / 7 h / Heating

2: 59 percent / MnO₂ / CH₂Cl₂ / 3 h / 20 °C

With manganese(IV) oxide; In dichloromethane; acetonitrile;

DOI:10.1021/ol052403f

upstream raw materials:

tert-butyl 2-(4-nitrophenyl)hydrazine-1-carboxylate

di-tert-butyl dicarbonate

4-nitrophenylhydrazone

N-(tert-butyloxycarbonyl) azide

Downstream raw materials:

C₃₄H₄₂N₄O₇

C₃₁H₃₅N₃O₇

C₃₄H₄₀N₄O₈

tert-butyl 2-(4-(4’-fluorophenoxy)phenyl)azocarboxylate