4-Tetradecanol

Base Information

• Chemical Name: 4-Tetradecanol
• CAS No.: 1653-33-4
• Molecular Formula: C14H30 O
• Molecular Weight: 214.392
• Hs Code.: 2905199090
• European Community (EC) Number: 216-724-7
• DSSTox Substance ID: DTXSID20937061
• Nikkaji Number: J112.119G
• Wikidata: Q82913262
• Mol file: 1653-33-4.mol

Synonyms:4-Tetradecanol;Tetradecan-4-ol;1653-33-4;EINECS 248-318-0;EINECS 216-724-7;AI3-35273;27196-00-5;4-tetradecyl alcohol;SCHEMBL378768;DTXSID20937061;AKOS012404026;LS-148908

Chemical Property of 4-Tetradecanol

Chemical Property:

• Vapor Pressure: 0.000628mmHg at 25°C
• Melting Point: 24 °C
• Refractive Index: 1.4237 (estimate)
• Boiling Point: 275.7°Cat760mmHg
• PKA: 15.27±0.20(Predicted)
• Flash Point: 110.4°C
• PSA: 20.23000
• Density: 0.832g/cm³
• LogP: 4.67820
• XLogP3: 6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 11
• Exact Mass: 214.229665576
• Heavy Atom Count: 15
• Complexity: 112

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCC(CCC)O

Technology Process of 4-Tetradecanol

There total 10 articles about 4-Tetradecanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1,3-Dimethyl-2-[((E)-1-propenyl)-undecyloxymethyl]-benzene (699008-01-0) → tetradecan-4-ol (1653-33-4) + 4-(2',6'-dimethylbenzyl)oxytetradecane

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethanol; at 20 ℃; for 4h; atmospheric pressure;

DOI:10.1055/s-2004-815977

Reference yield: 60.0%

[((E)-1-Propenyl)-undecyloxymethyl]-benzene → tetradecan-4-ol (1653-33-4) + 4-benzyloxytetradecane

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethanol; at 20 ℃; for 4h; atmospheric pressure;

DOI:10.1055/s-2004-815977

Reference yield:

tetradecane (629-59-4) → 3-tetradecanol (1653-32-3,4476-77-1) + 1-Tetradecanol (112-72-1) + 6-tetradecanol (6836-39-1) + 5-tetradecanol (21078-83-1) + tetradecan-4-ol (1653-33-4) + tetradecan-2-ol (4706-81-4)

Guidance literature:

With iodosylbenzene; MnTTPPP(OAc); In benzene; at 25 ℃; for 7h; Mechanism; other catalysts and regioselectivity investigated;

DOI:10.1021/ja00283a024

upstream raw materials:

undecylaldehyde

n-propylmagnesium bromide

tetradecan-4-one

n-decyl magnesium bromide

Refernces

• 1、 Cook, Bruce R.,Reinert, Thomas J.,Suslick, Kenneth S.. "Shape Selective Alkane Hydroxylation by Metalloporphyrin Catalysts". . p. 7281 - 7286. Retrieved 2007/10/02.