4-ACETOXYSTILBENE

Base Information

• Chemical Name: 4-ACETOXYSTILBENE
• CAS No.: 93022-30-1
• Molecular Formula: C16H14O2
• Molecular Weight: 238.28100
• Mol file: 93022-30-1.mol

Synonyms:Phenol, 4-(2-phenylethenyl)-, acetate;4-Stilbenol, acetate;4-ACETOXYSTILBENE;

Chemical Property of 4-ACETOXYSTILBENE

Chemical Property:

• Melting Point: 134-135 °C
• Boiling Point: 365.8±17.0 °C (760 mmHg)
• PSA: 26.30000
• Density: 1.133±0.06 g/cm3 (20 °C, 760 mmHg)
• LogP: 3.78230

Purity/Quality:

99% ^*data from raw suppliers

4-Acetoxystilbene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-ACETOXYSTILBENE

There total 29 articles about 4-ACETOXYSTILBENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

iodobenzene (591-50-4) + p-acetoxystyrene (2628-16-2) → Trans-acetic acid 4-styrylphenyl ester (93022-30-1,13041-73-1)

Guidance literature:

With triethylamine; poly{bis[(N-iPr-acrylamide)5-co-((4-vinylphenyl)PPh₂)]PdCl₂}; In toluene; at 100 ℃; for 20h;

DOI:10.1016/j.tet.2004.02.068

Reference yield: 89.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 4-acetoxyiodobenzene (33527-94-5) → 4-[-2-phenylethenyl]phenyl acetate (93022-30-1)

Guidance literature:

With potassium hydroxide; In water; N,N-dimethyl-formamide; at 120 ℃; for 24h;

DOI:10.1039/c6ra09996c

Reference yield: 86.0%

4-[(Z)-2-phenylethenyl]phenyl acetate (674368-06-0) → Trans-acetic acid 4-styrylphenyl ester (93022-30-1,13041-73-1)

Guidance literature:

With iodine; In hexane; for 1h; Reflux;

DOI:10.1016/j.bioorg.2016.01.001

upstream raw materials:

styrene

4-acetoxyiodobenzene

iodobenzene

p-acetoxystyrene

Downstream raw materials:

4-[(Z)-2-phenylethenyl]phenyl acetate

(trans-2,4-diphenylcyclobutane-1,3-diyl)dibenzene-4,1-diyl diacetate

(cis-2,4-diphenylcyclobutane-1,3-diyl)dibenzene-4,1-diyl diacetate

[(1RS,2SR,3RS,4SR)-3,4-diphenylcyclobutane-1,2-diyl]dibenzene-4,1-diyl diacetate

Refernces

• 1、 Malunavar, Shruti S.,Sutar, Suraj M.,Prabhala, Pavankumar,Kalkhambkar, Rajesh G.,Laali, Kenneth K.. "Ionic liquid-mediated benzoyl transfer-coupling in the Suzuki and Sonogashira reactions and aryl transfer-coupling by decarbonylative Heck reaction, using N-Benzoyl-saccharin (NBSac) as reagent". supporting information. . Retrieved 2020/05/18.
• 2、 Rao, Santhosh,Prabhu, Kandikere Ramaiah. "Stereodivergent Alkyne Reduction by using Water as the Hydrogen Source". supporting information. p. 13954 - 13962. Retrieved 2018/09/14.