Phenol,2-[(2-thienylmethylene)amino]-

Base Information

• Chemical Name: Phenol,2-[(2-thienylmethylene)amino]-
• CAS No.: 1435-04-7
• Molecular Formula: C11H9 N O S
• Molecular Weight: 203.265
• Mol file: 1435-04-7.mol

Synonyms:Phenol,o-(2-thenylideneamino)- (7CI,8CI); NSC 249302;o-(N-Thiophene-2-aldimino)phenol; o-(N-a-Thiophene-2-aldimino)phenol;o-(Thiophene-2-aldimino)phenol

Chemical Property of Phenol,2-[(2-thienylmethylene)amino]-

Chemical Property:

• Vapor Pressure: 1.69E-06mmHg at 25°C
• Boiling Point: 385.6°Cat760mmHg
• Flash Point: 187°C
• PSA: 60.83000
• Density: 1.2g/cm³
• LogP: 3.20430

Purity/Quality:

98%min ^*data from raw suppliers

2-([(Z)-THIOPHEN-2-YLMETHYLIDENE]AMINO)PHENOL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phenol,2-[(2-thienylmethylene)amino]-

There total 2 articles about Phenol,2-[(2-thienylmethylene)amino]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thiophene-2-carbaldehyde (98-03-3) + 2-amino-phenol (95-55-6) → 2-[(E)-(thiophen-2-ylmethylidene)amino]phenol (1435-04-7)

Guidance literature:

With acetic acid;

DOI:10.1021/ja01108a034

Reference yield:

2-[(E)-(thiophen-2-ylmethylidene)amino]phenol (1435-04-7) → 2-thiophen-2-yl-benzooxazole (23999-63-5) + 2-Thiophen-2-yl-2,3-dihydro-benzooxazole (71173-45-0) + cis-N-(2-Thienylmethylene)-o-aminophenol (1435-04-7)

Guidance literature:

In methyl cyclohexane; Title compound not separated from byproducts; Ambient temperature; Irradiation;

DOI:10.1021/jo00334a029

Reference yield: 69.0%

2-[(E)-(thiophen-2-ylmethylidene)amino]phenol (1435-04-7) + C19H22ClNOSi (1000026-07-2) → 2-((1R,2R)-2-phenyl-1-(thiophen-2-yl)-but-3-enylamino)phenol (1000026-15-2)

Guidance literature:

In dichloromethane; 1,2-dichloro-ethane; Heating;

DOI:10.1021/ja076035h

upstream raw materials:

thiophene-2-carbaldehyde

2-amino-phenol

Downstream raw materials:

2-thiophen-2-yl-benzooxazole

2-Thiophen-2-yl-2,3-dihydro-benzooxazole