Benzenecarbodithioic acid ethyl ester

Base Information

• Chemical Name: Benzenecarbodithioic acid ethyl ester
• CAS No.: 936-63-0
• Molecular Formula: C9H10S2
• Molecular Weight: 182.31
• Hs Code.: 2930909090
• Mol file: 936-63-0.mol

Synonyms:Dithiobenzoesaeure-aethylester;Benzoic acid,dithio-,ethyl ester;Aethyldithiobenzoat;S-ethyl dithiobenzoate;Dithiobenzoesaeure-ethylester;dithiobenzoic acid ethyl ester;ethyl dithiobenzoate;Thiobenzoesaeure-ethylthioester;Benzenecarbodithioic acid,ethyl ester;

Chemical Property of Benzenecarbodithioic acid ethyl ester

Chemical Property:

• PSA: 57.39000
• LogP: 3.11520

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenecarbodithioic acid ethyl ester

There total 34 articles about Benzenecarbodithioic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

O-(1-(N,4-dimethylphenylsulfonamido)vinyl) benzothioate + ethanethiol (75-08-1) → S-ethyl dithiobenzoate (936-63-0)

Guidance literature:

With caesium carbonate; In acetonitrile; for 0.0833333h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.orglett.0c02402

Reference yield: 79.0%

benzoic acid ethyl ester (93-89-0,99341-95-4) → Thiobenzoic acid O-ethyl ester (936-61-8) + S-ethyl dithiobenzoate (936-63-0)

Guidance literature:

With Lawessons reagent; In xylene; for 10h; Heating;

Reference yield: 77.0%

thiobenzoic acid, anhydrosulfide with O,O-diethyl dithiophosphorate (1497-32-1) + O,O-Diethyl hydrogen phosphorodithioate (298-06-6) → S-ethyl dithiobenzoate (936-63-0)

Guidance literature:

at 200 ℃; for 0.1h;

DOI:10.1016/S0040-4020(01)96883-8

upstream raw materials:

ethyl thiobenzimidate

O-ethyl S-benzoyl xanthate

thiobenzoyl chloride

ethanethiol

Downstream raw materials:

N,N'-Dicyan-benzamidin-kalium

Thioessigsaeure-S-(α-ethylbenzylester)

benzaldehyde diethyldithioacetal

2-phenyl-2-imidazoline

Refernces

• 1、 Hewitt, Russell J.,Ong, Michelle Jui Hsien,Lim, Yi Wee,Burkett, Brendan A.. "Investigations of the Thermal Responsiveness of 1,4,2-Oxathiazoles". supporting information. p. 6687 - 6700. Retrieved 2015/10/29.
• 2、 Yousif, N. M.. "THE REACTION OF CARBOXYLIC ACID CHLORIDES WITH O,O-DIALKYLDITHIOPHOSPHORIC ACIDS". . p. 79 - 82. Retrieved 2007/10/02.