1-(Bromomethyl)-4-(methoxymethyl)benzene

Base Information

Chemical Name:1-(Bromomethyl)-4-(methoxymethyl)benzene
CAS No.:95349-71-6
Molecular Formula:C9H11BrO
Molecular Weight:215.09
Hs Code.:
European Community (EC) Number:960-490-5
Nikkaji Number:J2.448.106I

Synonyms:1-(bromomethyl)-4-(methoxymethyl)benzene;4-methoxymethylbezylbromide;95349-71-6;SCHEMBL4371209;CPGGWEMHYNBPPD-UHFFFAOYSA-N;AKOS014962178;CS-0238193;FT-0760306;EN300-1912125

Suppliers and Price of 1-(Bromomethyl)-4-(methoxymethyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 1-(Bromomethyl)-4-(methoxymethyl)benzene

Chemical Property:

XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:213.99933
Heavy Atom Count:11
Complexity:97.7

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COCC1=CC=C(C=C1)CBr

Technology Process of 1-(Bromomethyl)-4-(methoxymethyl)benzene

There total 2 articles about 1-(Bromomethyl)-4-(methoxymethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.4%

: 62172-89-8
4-methyloxymethylhydroxymethylhydroxymethylcyclohexane

: 95349-71-6
1-(bromomethyl)-4-(methoxymethyl)benzene

Guidance literature:: With N-Bromosuccinimide; dimethylsulfide; In dichloromethane; at -20 - 20 ℃;
DOI:10.1021/ol0629770

Reference yield:

: 589-29-7
p-xylylene glycol

: 95349-71-6
1-(bromomethyl)-4-(methoxymethyl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / tetrahydrofuran / 0.5 h

1.2: 70.2 percent Turnov_. / tetrahydrofuran

2.1: 92.4 percent / N-bromosuccinimide; Me₂S / CH₂Cl₂ / -20 - 20 °C

With N-Bromosuccinimide; dimethylsulfide; sodium hydride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ol0629770

Reference yield: 74.0%

: 95349-71-6
1-(bromomethyl)-4-(methoxymethyl)benzene

: 934667-38-6
((4-(bromomethyl)benzyl)oxy)triisopropylsilane

: 934667-43-3
1-(4-(triisopropylsilanyloxymethyl)phenyl)-3-(4-methoxymethylphenyl)-propan-2-one

Guidance literature:: 1-(bromomethyl)-4-(methoxymethyl)benzene; Na₂Fe(CO)4; In various solvent(s); at 0 - 20 ℃;

((4-(bromomethyl)benzyl)oxy)triisopropylsilane; In various solvent(s); at 45 ℃; for 18h; Further stages.;
DOI:10.1021/ol0629770