4,7-Bis(4-Methoxyphenyl)-1,10-phenanthroline

Base Information

• Chemical Name: 4,7-Bis(4-Methoxyphenyl)-1,10-phenanthroline
• CAS No.: 95950-20-2
• Molecular Formula: C26H20N2O2
• Molecular Weight: 392.44900
• Hs Code.: 2933990090
• Mol file: 95950-20-2.mol

Synonyms:

Chemical Property of 4,7-Bis(4-Methoxyphenyl)-1,10-phenanthroline

Chemical Property:

• PSA: 44.24000
• LogP: 6.13420
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

4,7-Bis(4-methoxyphenyl)-1,10-phenanthroline 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4,7-Bis(4-Methoxyphenyl)-1,10-phenanthroline

There total 9 articles about 4,7-Bis(4-Methoxyphenyl)-1,10-phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4,7-dichloro-1,10-phenanthroline (5394-23-0) + 4-methoxyphenylboronic acid (5720-07-0) → 4,7-bis-(p-methoxyphenyl)-1,10-phenanthroline (95950-20-2)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; caesium carbonate; tricyclohexylphosphine; In 1,4-dioxane; water; at 100 ℃; for 3.5h; Inert atmosphere;

DOI:10.1021/acs.joc.1c02425

Reference yield: 67.0%

3-chloro-4'-methoxypropiophenone (35999-20-3) + 8-amino-4-(4'-methoxyphenyl)quinoline (93013-59-3) → 4,7-bis-(p-methoxyphenyl)-1,10-phenanthroline (95950-20-2)

Guidance literature:

With arsenic(V) oxide; phosphoric acid; at 140 ℃; for 1h;

DOI:10.1002/ejic.200500176

Reference yield: 14.0%

3-chloro-4'-methoxypropiophenone (35999-20-3) + 1,2-diamino-benzene (95-54-5) → 4,7-bis-(p-methoxyphenyl)-1,10-phenanthroline (95950-20-2)

Guidance literature:

1,2-diamino-benzene; With hydrogenchloride; at 60 - 90 ℃; Inert atmosphere;

3-chloro-4'-methoxypropiophenone; for 2h; Inert atmosphere;

With sulfuric acid; Inert atmosphere;

DOI:10.1039/d1nj04955k

upstream raw materials:

3-chloro-4'-methoxypropiophenone

8-amino-4-(4'-methoxyphenyl)quinoline

4-(4'-methoxyphenyl)-8-nitroquinoline

methoxybenzene

Downstream raw materials:

4,7-bis(4'-hydroxyphenyl)-1,10-phenanthroline

Os(4,7-bis(4-methoxyphenyl)-1,10-phenanthroline)2Cl₂