Cerium trichloride

Base Information

• Chemical Name: Cerium trichloride
• CAS No.: 7790-86-5
• Deprecated CAS: 1082111-62-3
• Molecular Formula: CeCl3
• Molecular Weight: 246.479
• Hs Code.: 2846109090
• NSC Number: 84267
• Wikidata: Q419806
• Mol file: 7790-86-5.mol

Synonyms:trichlorocerium;Cerium chloride (CeCl3);Cerium(III) Chloride, Anhydrous;Cerium(III) chloride beads;Cerium(III) chloride powder;MFCD00010929;trichloridocerium;cerium(3+) chloride;Cerium chloride, CeCl3;[CeCl3];WLN: CE G3;CHEBI:35458;Cerium(III) chloride, ultra dry;NSC84267;Cerium(III) chloride, anhydrous,CeCl3;SC10975;Cerium(III) chloride, anhydrous (H2O < 0.5%);Q419806;Cerium(III) chloride, anhydrous, beads, -10 mesh, 99.9%;Cerium (III) chloride, ultra dry, powder, ampoule, 99.9% trace metals basis;Cerium(III) chloride, anhydrous, beads, -10 mesh, >=99.99% trace metals basis;CERIUM CHLORIDE;CERIUM TRICHLORIDE;CERIUM(III) CHLORIDE;CEROUS CHLORIDE;Cerium(III) chloride, anhydrous,??CeCl3

Chemical Property of Cerium trichloride

Chemical Property:

• Appearance/Colour: white powder
• Melting Point: 848 °C(lit.)
• Boiling Point: 1727 °C
• Flash Point: 1727°C
• PSA: 0.00000
• Density: 3.97 g/mL at 25 °C(lit.)
• LogP: -8.98800
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 244.81201
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi:Irritant
• Statements: R36/37/38:
• Safety Statements: S26:; S36:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: Cl[Ce](Cl)Cl
• Use Description: Ceramics containing cerium(III) chloride (CeCl3) have several applications in different fields. In the field of materials science and engineering, these ceramics can be used to produce scintillation detectors and phosphors. The presence of cerium(III) ions imparts luminescent properties to the ceramics, making them suitable for use in radiation detection and imaging applications, such as in nuclear physics research and medical diagnostics. In the field of catalysis and chemical synthesis, cerium(III) chloride can be used as a catalyst or co-catalyst in various chemical reactions, including those involved in the production of fine chemicals and pharmaceuticals. Its role in catalysis can enhance reaction rates and selectivity, contributing to the development of more efficient and sustainable chemical processes. Its adaptability as a luminescent material and catalyst underscores its significance in advancing radiation detection, materials science, and chemical synthesis in various fields.

Technology Process of Cerium trichloride

There total 47 articles about Cerium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

([Ce(μ-Cl)(H2O)7](Cl)2)2 → cerium chloride (7790-86-5,15785-07-6)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Ce compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield: 96.4%

cerium(III) sulfate pentahydrate + ammonium chloride → cerium chloride (7790-86-5,15785-07-6)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O, NH3; a mixt. of Ce-contg. compd. and NH4Cl (2.5-fold excess) was gradually heated to 830°C under He for 12 h; chem. anal.;

DOI:10.1023/A:1027341307451

Reference yield: 96.0%

cerium(IV) oxide → cerium chloride (7790-86-5,15785-07-6)

Guidance literature:

With HCl; In hydrogenchloride; formic acid; (N2 or Ar); stirring the mixt. of CeO2, HCl (37 %) and HCOOH under reflux for 24 h;; evapn. of the soln. to dryness; dehydration of the remaining solid under vacuum (0.01 mm Hg) at ca. 170°C; for 48 h; elem. anal.;;

DOI:10.1021/om00102a011

upstream raw materials:

cerium(III) chloride heptahydrate

cerium chloride monohydrate

cerium(III) chloride hydrate

phosgene

Downstream raw materials:

2-benzyl-6-methoxy-1-tetralol

1,1-dimethylethyl 4-[2-oxo-3-(4-pyridinyl)propyl]-1-piperidinecarboxylate

(10-Methoxymethyl-10H-pyrazino[2,3-b][1,4]benzothiazin-8-yl)-[1-(triphenylmethyl)imidazol-2-yl]methanol

cerium

Refernces

• 1、 Hu, Shanshan,Jiang, Li,Mao, Yini,Wang, Zhiyi,Yang, Jun,Ye, Rui. "The morphology evolution, tunable down-conversion luminescence, and energy transfer of [CaY]F2crystals doped with Li+/Ce3+/Tb3+". . p. 15433 - 15442. Retrieved 2020/11/18.
• 2、 Peng, Di,Huang, Mengjun,Xiao, Yaruo,Zhang, Yuyan,Lei, Li,Zhu, Jiang. "Highly-selective recognition of latent fingermarks by La-sensitized Ce nanocomposites: Via electrostatic binding". supporting information. p. 10579 - 10582. Retrieved 2019/09/12.