trans-9,10-Dihydrophenanthrene-9,10-dicarboxylic acid

Base Information

• Chemical Name: trans-9,10-Dihydrophenanthrene-9,10-dicarboxylic acid
• CAS No.: 2510-70-5
• Molecular Formula: C₁₆H₁₂O₄
• Molecular Weight: 268.269
• NSC Number: 29072
• Nikkaji Number: J707.229E
• Mol file: 2510-70-5.mol

Synonyms:2510-70-5;NSC29072;trans-9,10-dihydrophenanthrene-9,10-dicarboxylic acid;NSC-29072

Chemical Property of trans-9,10-Dihydrophenanthrene-9,10-dicarboxylic acid

Chemical Property:

• Vapor Pressure: 7.86E-13mmHg at 25°C
• Boiling Point: 547.7°Cat760mmHg
• Flash Point: 299.1°C
• PSA: 74.60000
• Density: 1.407g/cm³
• LogP: 2.70360
• XLogP3: 2.3
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 268.07355886
• Heavy Atom Count: 20
• Complexity: 367

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(C(C3=CC=CC=C32)C(=O)O)C(=O)O
• Isomeric SMILES: C1=CC=C2C(=C1)[C@H]([C@@H](C3=CC=CC=C32)C(=O)O)C(=O)O

Technology Process of trans-9,10-Dihydrophenanthrene-9,10-dicarboxylic acid

There total 5 articles about trans-9,10-Dihydrophenanthrene-9,10-dicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

carbon dioxide (124-38-9,18923-20-1) + phenanthrene (85-01-8) → 9,10-dihydroxyphenanthrene-9-carboxylic acid (2222-30-2) + phenanthrene-9-carboxylic acid (837-45-6) + trans-9,10-dihydrophenanthrene-9,10-dicarboxylic acid (2510-70-5,22333-19-3,92965-14-5) + 10--9,10-dihydrophenanthrene-9-carboxylic acid

Guidance literature:

With N,N-dimethyl-aniline; In dimethyl sulfoxide; for 1.5h; under 380 - 36480 Torr; Product distribution; Mechanism; Quantum yield; Irradiation; effect of cumene, water, pressure of CO₂;

DOI:10.1021/jo951702n

Reference yield:

phenanthrene (85-01-8) → trans-9,10-dihydrophenanthrene-9,10-dicarboxylic acid (2510-70-5,22333-19-3,92965-14-5)

Guidance literature:

With 1,2-dimethoxyethane; sodium; Einleiten von Kohlendioxid in die Reaktionsloesung;

DOI:10.1021/ja01291a041

Reference yield:

cis-9,10-dihydro-phenanthrene-dicarboxylic acid-(9.10) (22333-19-3) → trans-9,10-dihydrophenanthrene-9,10-dicarboxylic acid (2510-70-5,22333-19-3,92965-14-5)

Guidance literature:

With sodium hydroxide;

DOI:10.1021/ja01291a041

upstream raw materials:

phenanthrene

cis-9,10-dihydro-phenanthrene-dicarboxylic acid-(9.10)

(E)-9,10-dicyano-9,10-dihydrophenanthrene

carbon dioxide

Downstream raw materials:

9,10-phenanthrenequinone

Refernces