1,7,7-Trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one

Base Information

Chemical Name:1,7,7-Trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one
CAS No.:15087-24-8
Molecular Formula:C17H20O
Molecular Weight:240.345
Hs Code.:2914399090
European Community (EC) Number:239-139-9
Mol file:15087-24-8.mol

Synonyms:1,7,7-trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one;W-110402

Suppliers and Price of 1,7,7-Trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3-Benzylidenecamphor
250mg
$ 180.00

TRC
3-Benzylidenecamphor
50mg
$ 110.00

Sigma-Aldrich
3-Benzylidenecamphor analytical standard
25mg
$ 91.00

Total 34 raw suppliers

Chemical Property of 1,7,7-Trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one

Chemical Property:

Vapor Pressure:3.34E-05mmHg at 25°C
Melting Point:97 °C
Refractive Index:1.589
Boiling Point:354.5 °C at 760 mmHg
Flash Point:158.2 °C
PSA：17.07000
Density:1.079 g/cm³
LogP:4.09520
Storage Temp.:Refrigerator
Solubility.:Chloroform (Sparingly), Hexanes (Slightly), Methanol (Slightly)
XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:240.151415257
Heavy Atom Count:18
Complexity:398

Purity/Quality:

99.9% ^*data from raw suppliers

3-Benzylidenecamphor ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 63-62
Safety Statements: 36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2CCC1(C(=O)C2=CC3=CC=CC=C3)C)C
Isomeric SMILES:C[C@]12CC[C@H](C1(C)C)/C(=C/C3=CC=CC=C3)/C2=O
Uses 3-benzylidene camphor is a sunscreen chemical with uVB-filtering and absorption capacities with an approved usage level of up to 2 percent in the european union.

Technology Process of 1,7,7-Trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one

There total 24 articles about 1,7,7-Trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: phenylmagnesium bromide

: 473929-46-3
(1R,4R)-3-[(E)-(dimethylamino)methylidene]-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

: 15087-24-8,28070-26-0,31020-79-8,36065-09-5,36065-10-8,36275-29-3,79389-58-5,79389-62-1
(1R,4S,3E)-3-benzylidene-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

Guidance literature:: In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1016/j.tetasy.2006.04.014

Reference yield: 85.0%

: 736109-58-3,787517-91-3,68546-28-1
1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one

: 100-51-6,185532-71-2
benzyl alcohol

: 15087-24-8
3-benzylidene-dl-camphor

Guidance literature:: With 1,10-Phenanthroline; iron(II) acetate; sodium t-butanolate; In toluene; at 110 ℃; for 24h; Schlenk technique; Sealed tube; Inert atmosphere;
DOI:10.3390/molecules25071590