5-Aza-2,8,9-trioxa-1-bismabicyclo(3.3.3)undecane

Base Information

Chemical Name:5-Aza-2,8,9-trioxa-1-bismabicyclo(3.3.3)undecane
CAS No.:283-55-6
Molecular Formula:Bi*C₆H₁₂NO₃
Molecular Weight:355.147
Hs Code.:
DSSTox Substance ID:DTXSID80182550
Mol file:283-55-6.mol

Synonyms:283-55-6;5-AZA-2,8,9-TRIOXA-1-BISMABICYCLO(3.3.3)UNDECANE;DTXSID80182550

Suppliers and Price of 5-Aza-2,8,9-trioxa-1-bismabicyclo(3.3.3)undecane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 5-Aza-2,8,9-trioxa-1-bismabicyclo(3.3.3)undecane

Chemical Property:

Boiling Point:335.4°Cat760mmHg
Flash Point:185°C
Density:g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:355.06212
Heavy Atom Count:11
Complexity:111

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CO[Bi]2OCCN1CCO2

Technology Process of 5-Aza-2,8,9-trioxa-1-bismabicyclo(3.3.3)undecane

There total 3 articles about 5-Aza-2,8,9-trioxa-1-bismabicyclo(3.3.3)undecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 102-71-6,64114-46-1
triethanolamine

: 1304-76-3
bismuth(III) oxide

: 26151-44-0,283-55-6
[Bi(triethanolaminolate)]n

Guidance literature:: In toluene; byproducts: H2O; under inert atm., 5 equiv. of the amine, reflux for 5 d; soln. was filtered, evapd., recrystn. from hot toluene at room temp., elem. anal,;
DOI:10.1016/j.inoche.2006.09.012

Reference yield:

: 46140-16-3
bismuth(III) nitrate

: 102-71-6,64114-46-1
triethanolamine

: 26151-44-0,283-55-6
[Bi(triethanolaminolate)]n

Guidance literature:: With nitric acid; NaOH; NaOEt; In water; Bi(NO3)3 dissolved in dilute nitric acid, aq. soln. of NaOH added under vigorous stiring, ppt. filtered off and added to soln. of EtONa in EtOH,triethanolamine added, heated to 65-70°C overnight; allowed to cool to room temp., charcoal added and filtered through silica, filtrate diluted with MeOH, allowed to stand for several weeks;
DOI:10.1016/S0020-1693(02)01381-6