Dihydroxy(oxo)ammonium; diphenyliodonium

Base Information

• Chemical Name: Dihydroxy(oxo)ammonium; diphenyliodonium
• CAS No.: 722-56-5
• Molecular Formula: C₁₂H₁₀I*NO₃
• Molecular Weight: 343.121
• Hs Code.: 29319090
• NSC Number: 90597
• Mol file: 722-56-5.mol

Synonyms:NSC90597;NSC-90597;dihydroxy(oxo)ammonium;diphenyliodonium;A837466;bis(oxidanyl)-oxidanylidene-azanium;diphenyliodanium

Chemical Property of Dihydroxy(oxo)ammonium; diphenyliodonium

Chemical Property:

• Appearance/Colour: White to greyish fine crystalline powder
• Melting Point: 147 ºC
• PSA: 68.88000
• Density: 1.7164 (estimate)
• LogP: 0.09910
• Sensitive.: Light Sensitive
• Solubility.: soluble in Methanol
• Water Solubility.: Soluble in hot water
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 344.98619
• Heavy Atom Count: 17
• Complexity: 142

Purity/Quality:

99% ^*data from raw suppliers

Diphenyliodinium nitrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O
• Hazard Codes: O
• Statements: 8
• Safety Statements: 17-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[I+]C2=CC=CC=C2.[N+](=O)(O)O

Technology Process of Dihydroxy(oxo)ammonium; diphenyliodonium

There total 4 articles about Dihydroxy(oxo)ammonium; diphenyliodonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

diphenyliodonium iodide (2217-79-0) → diphenyliodonium nitrate (722-56-5)

Guidance literature:

With dihydrogen peroxide; nitric acid; In ethanol; water; Heating;

DOI:10.1246/bcsj.70.219

Reference yield: 75.0%

diphenyliodonium bromide (1483-73-4) → diphenyliodonium nitrate (722-56-5)

Guidance literature:

With dihydrogen peroxide; nitric acid; In methanol; cyclohexene; Heating;

DOI:10.1055/s-1995-4045

Reference yield:

iodobenzene (591-50-4) → diphenyliodonium nitrate (722-56-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 55 percent / 1.5 h / 50 °C

2: 78 percent / H₂O₂, HNO₃ / aq. ethanol; H₂O / Heating

With dihydrogen peroxide; nitric acid; In ethanol; water;

DOI:10.1246/bcsj.70.219

upstream raw materials:

diphenyliodonium bromide

diphenyliodonium iodide

iodobenzene

benzene

Refernces

• 1、 Kazmierczak,Skulski. "A short-cut synthesis of diaryliodonium bromides followed by oxidative anion metatheses". . p. 1027 - 1032. Retrieved 2007/10/02.