4-Phenanthrenemethanol

Base Information

• Chemical Name: 4-Phenanthrenemethanol
• CAS No.: 22863-79-2
• Molecular Formula: C15H12 O
• Molecular Weight: 208.26
• Hs Code.: 2906299090
• European Community (EC) Number: 245-270-2
• DSSTox Substance ID: DTXSID60945549
• Nikkaji Number: J83.229D
• Wikidata: Q82922929
• Mol file: 22863-79-2.mol

Synonyms:4-Phenanthrenemethanol;Phenanthren-4-methanol;22863-79-2;EINECS 245-270-2;4-Phenanthrylmethanol;4-Phenanthrenmethanol;4-Phenanthrylmethanol #;Phenanthrenemethanol, 4-;4-(Hydroxymethyl)phenanthrene;SCHEMBL8622874;DTXSID60945549;(PHENANTHREN-4-YL)METHANOL;AKOS024333061

Chemical Property of 4-Phenanthrenemethanol

Chemical Property:

• Vapor Pressure: 6.35E-08mmHg at 25°C
• Boiling Point: 423.4°Cat760mmHg
• Flash Point: 196.3°C
• PSA: 20.23000
• Density: 1.214g/cm³
• LogP: 3.48530
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 208.088815002
• Heavy Atom Count: 16
• Complexity: 238

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC3=C2C(=CC=C3)CO

Technology Process of 4-Phenanthrenemethanol

There total 3 articles about 4-Phenanthrenemethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-bromomethyl-phenanthrene (93065-12-4) → 4‐phenanthrenemethanol (22863-79-2)

Guidance literature:

With potassium acetate; acetic acid; Erhitzen des Reaktionsprodukts mit wss.-aethanol. KOH;

DOI:10.1002/hlca.19550380740

Reference yield:

phenanthrene-4-carboxylic acid methyl ester (18266-47-2) → 4‐phenanthrenemethanol (22863-79-2)

Guidance literature:

With lithium aluminium tetrahydride;

Reference yield:

4-methylphenanthrene (832-64-4) → 4‐phenanthrenemethanol (22863-79-2)

Guidance literature:

Multi-step reaction with 2 steps

1: dibenzoyl peroxide; CCl₄; N-bromo-succinimide

2: potassium acetate; acetic acid / Erhitzen des Reaktionsprodukts mit wss.-aethanol. KOH

With tetrachloromethane; N-Bromosuccinimide; potassium acetate; acetic acid; dibenzoyl peroxide;

DOI:10.1002/hlca.19550380740

upstream raw materials:

4-bromomethyl-phenanthrene

phenanthrene-4-carboxylic acid methyl ester

4-methylphenanthrene

Downstream raw materials:

4-Phenanthrencarbaldehyd