3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl methacrylate

Base Information

• Chemical Name: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl methacrylate
• CAS No.: 1996-88-9
• Deprecated CAS: 119938-07-7,123203-95-2,128809-13-2,140143-15-3,162953-65-3,203868-08-0,122197-02-8,224636-16-2,270060-88-3,122197-02-8,123203-95-2,128809-13-2,140143-15-3,162953-65-3,203868-08-0,270060-88-3
• Molecular Formula: C14H9F17O2
• Molecular Weight: 532.197
• Hs Code.: 29161400
• European Community (EC) Number: 217-877-2
• DSSTox Substance ID: DTXSID8062101
• Nikkaji Number: J106.003A
• Wikidata: Q72500617
• Mol file: 1996-88-9.mol

Synonyms:10-2 fluorotelomer methacrylate;10:2 fluorotelomer methacrylate;10:2 FTMAC;3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl 2-methylprop-2-enoate;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl 2-methylprop-2-enoate;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Henicosafluorododecyl 2-methylprop-2-enoate;6-2 fluorotelomer methacrylate;6:2 fluorotelomer methacrylate;6:2 FTMAC;8-2 fluorotelomer methacrylate;8:2 fluorotelomer methacrylate;8:2 FTMAC;fluorotelomer methacrylate;fluorotelomer methacrylate polymers;FTMAC fluorotelomer methacrylate polymers

Chemical Property of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl methacrylate

Chemical Property:

• Vapor Pressure: 0.0199mmHg at 25°C
• Melting Point: -20°C
• Refractive Index: n20/D 1.343(lit.)
• Boiling Point: 251.9 °C at 760 mmHg
• Flash Point: 103.1 °C
• PSA: 26.30000
• Density: 1.516 g/cm³
• LogP: 6.50520
• Storage Temp.: Keep Cold
• Solubility.: Chloroform (Sparingly), Methanol (Slightly)
• XLogP3: 7.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 19
• Rotatable Bond Count: 11
• Exact Mass: 532.0331083
• Heavy Atom Count: 33
• Complexity: 749

Purity/Quality:

99%, ^*data from raw suppliers

PerfluorooctylethylMethacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C, F, Xi
• Hazard Codes: C,F,Xi
• Statements: 34-42/43
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCCC(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Uses: Perfluorooctylethyl Methacrylate was used to prepare fluorinated latexes by polymerization of miniemulsions as fluorinated monomers.Along with Perfluorodecylethyl Methacrylate (P286590), Perfluorooctylethyl Methacrylate was one of the pollutants from Great Lakes studied.

Technology Process of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl methacrylate

There total 4 articles about 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

methacryloyl anhydride (760-93-0) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl methacrylate (1996-88-9)

Guidance literature:

With dmap; triethylamine; In dichloromethane; 1,1,2-Trichloro-1,2,2-trifluoroethane; at 30 ℃; for 18h;

DOI:10.1016/S0022-1139(96)03569-5

Reference yield: 60.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl methacrylate (1996-88-9)

Guidance literature:

With dicyclohexyl-carbodiimide; dmap; In 1,1,2-Trichloro-1,2,2-trifluoroethane; for 5h; Ambient temperature;

Reference yield:

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + 2-(n-perfluorooctyl)ethyl iodide (2043-53-0,71215-70-8) → 1H,1H,2H-perfluorodecene (21652-58-4) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl methacrylate (1996-88-9)

Guidance literature:

With silver(l) oxide; at 100 ℃; for 4h;

upstream raw materials:

poly(methacrylic acid)

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol

methacryloyl anhydride

2-(n-perfluorooctyl)ethyl iodide

Refernces

• 1、 Krupers, Maarten J.,Moeller, Martin. "Synthesis and characterization of semifluorinated polymers via group transfer polymerization". . p. 119 - 124. Retrieved 2007/10/03.