3-(Trichlorosilyl)propyl methacrylate

Base Information

• Chemical Name: 3-(Trichlorosilyl)propyl methacrylate
• CAS No.: 7351-61-3
• Molecular Formula: C7H11Cl3O2Si
• Molecular Weight: 261.608
• Hs Code.: 29319090
• European Community (EC) Number: 230-878-2
• UNII: 47R7ND8EC7
• DSSTox Substance ID: DTXSID5027647
• Nikkaji Number: J21.117F
• Wikidata: Q27259068
• ChEMBL ID: CHEMBL1882487
• Mol file: 7351-61-3.mol

Synonyms:3-(Trichlorosilyl)propyl methacrylate;7351-61-3;3-trichlorosilylpropyl 2-methylprop-2-enoate;2-Propenoic acid, 2-methyl-, 3-(trichlorosilyl)propyl ester;(3-Methacryloyloxypropyl)trichlorosilane;Methacrylic acid, 3-(trichlorosilyl)propyl ester;3-Methacryloxypropyltrichlorosilane;EINECS 230-878-2;UNII-47R7ND8EC7;47R7ND8EC7;DTXSID5027647;(3-methacryloxypropyl)trichlorosilane;C7H11Cl3O2Si;SCHEMBL476606;C7-H11-Cl3-O2-Si;DTXCID907647;CHEMBL1882487;methacryloxypropyl trichlorosilane;methacryloxypropyltrichloro-silane;Tox21_202567;MFCD00054720;gamma-methacryloxypropyltrichlorosilane;NCGC00164325-01;NCGC00260116-01;2-(2-PHENOXY-ETHOXY)-BENZOICACID;CAS-7351-61-3;LS-170284;TRICHLORO(3-METHACRYLOXYPROPYL)SILANE;(3-Methacryloyloxypropyl)Trichlorosilane, 90%;3-(trichlorosilyl)propyl 2-methylprop-2-enoate;E85360;(.GAMMA.-METHACRYLOXYPROPYL)TRICHLOROSILANE;(.GAMMA.-METHACRYLOYLOXYPROPYL)TRICHLOROSILANE;1-PROPANOL, 3-(TRICHLOROSILYL)-, METHACRYLATE;Q27259068;2-propenoic acid, 2-methyl-,3-(trichlorosilyl)propyl ester;3-(Trichlorosilyl)propyl methacrylate, technical, >=90% (GC);3-(Methacryloxy)propyltrichlorosilane,inhibited(3-Trichlorosilyl propylmethacrylate)

Chemical Property of 3-(Trichlorosilyl)propyl methacrylate

Chemical Property:

• Appearance/Colour: UN 2987
• Vapor Pressure: 0.00627mmHg at 25°C
• Refractive Index: n20/D 1.465(lit.)
• Boiling Point: 271.9 °C at 760 mmHg
• Flash Point: 118.3 °C
• PSA: 26.30000
• Density: 1.231g/cm³
• LogP: 3.15110
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 259.959389
• Heavy Atom Count: 13
• Complexity: 200

Purity/Quality:

98% ^*data from raw suppliers

3-(Trichlorosilyl)propyl methacrylate technical, ≥90% (GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 14-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=C)C(=O)OCCC[Si](Cl)(Cl)Cl

Technology Process of 3-(Trichlorosilyl)propyl methacrylate

There total 3 articles about 3-(Trichlorosilyl)propyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

allyl methacrylate (96-05-9) + trichlorosilane (10025-78-2) → 3-(trichlorosilyl)propyl 2-methylprop-2-enoate (7351-61-3)

Guidance literature:

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; In toluene; at 70 ℃; for 3h;

DOI:10.1016/j.jfluchem.2015.07.026

Reference yield: 88.0%

allyl methacrylate (96-05-9) → 3-(trichlorosilyl)propyl 2-methylprop-2-enoate (7351-61-3)

Guidance literature:

With dihydrogen hexachloroplatinate; 10H-phenothiazine; trichlorosilane; In tetrahydrofuran; at 80 ℃; for 0.5h;

Reference yield:

→ 3-(trichlorosilyl)propyl 2-methylprop-2-enoate (7351-61-3)

Guidance literature:

Allylmethacrylat, Trichlorsilan, Katalyse von Mesityloxid/PtCl2;

upstream raw materials:

allyl methacrylate

trichlorosilane

Downstream raw materials:

3-(triacetoxysilyl)propyl methacrylate

acetyl chloride

[3-(methacryloyloxy)propyl]trimethoxysilane

hexaethyl disiloxane

Refernces

• 1、 Cai, Lu,Li, Zhanxiong. "Synthesis and surface properties of novel fluoroalkylsilyl methacrylate copolymers". . p. 187 - 194. Retrieved 2015/08/19.
• 2、 -. "A METHOD OF MANUFACTURING AN ORGANIC SILICON COMPOUND THAT CONTAINS A METHACRYLOXY GROUP OR AN ACRYLOXY GROUP". Page/Page column 9. . Retrieved 2008/06/13.