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Trichlorosilane

Base Information Edit
  • Chemical Name:Trichlorosilane
  • CAS No.:10025-78-2
  • Molecular Formula:Cl3HSi
  • Molecular Weight:135.452
  • Hs Code.:28530090
  • European Community (EC) Number:233-042-5
  • ICSC Number:0591
  • UN Number:1295
  • Nikkaji Number:J8.976A
  • Wikipedia:Trichlorosilane
  • Wikidata:Q419041
  • Mol file:10025-78-2.mol
Trichlorosilane

Synonyms:trichlorosilane

Suppliers and Price of Trichlorosilane
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • Trichlorosilane
  • 25g
  • $ 85.00
  • Sigma-Aldrich
  • Trichlorosilane 99%
  • 100g
  • $ 49.00
  • Sigma-Aldrich
  • Trichlorosilane 99%
  • 5g
  • $ 30.00
  • Sigma-Aldrich
  • Trichlorosilane 99%
  • 500g
  • $ 125.00
  • Medical Isotopes, Inc.
  • Trichlorosilane
  • 25 g
  • $ 190.00
  • Alfa Aesar
  • Trichlorosilane 98%
  • 500g
  • $ 219.00
  • Alfa Aesar
  • Trichlorosilane 98%
  • 100g
  • $ 56.30
  • Alfa Aesar
  • Trichlorosilane 98%
  • 25g
  • $ 22.50
Total 27 raw suppliers
Chemical Property of Trichlorosilane Edit
Chemical Property:
  • Appearance/Colour:Clear liquid 
  • Vapor Pressure:9.75 psi ( 20 °C) 
  • Melting Point:-127 °C 
  • Refractive Index:1.4-1.402  
  • Boiling Point:31.8 °C at 760 mmHg 
  • Flash Point:-27 °C 
  • PSA:0.00000 
  • Density:1.34 g/cm3 
  • LogP:1.42000 
  • Storage Temp.:Refrigerator 
  • Sensitive.:Air & Moisture Sensitive 
  • Solubility.:Soluble in benzene, ether, heptane, chloroform and carbon tetrac 
  • Water Solubility.:decomposes 
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:0
  • Rotatable Bond Count:0
  • Exact Mass:133.891310
  • Heavy Atom Count:4
  • Complexity:8
  • Transport DOT Label:Dangerous When Wet Flammable Liquid Corrosive
Purity/Quality:

99% *data from raw suppliers

Trichlorosilane *data from reagent suppliers

Safty Information:
  • Pictogram(s): HighlyF+,Corrosive
  • Hazard Codes:F+,C 
  • Statements: 12-14-17-20/22-29-35 
  • Safety Statements: 16-26-36/37/39-43-45-7/9-43A 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Chemical Classes:Toxic Gases & Vapors -> Chlorosilanes
  • Canonical SMILES:[SiH](Cl)(Cl)Cl
  • Inhalation Risk:No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C.
  • Effects of Short Term Exposure:The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the vapour may cause lung oedema. Inhalation may cause asthma-like reactions. Exposure could cause death. Medical observation is indicated.
  • Uses It can be used the raw material for polymer organic silicon compound, it can also be used in industrial instrumentation. It can be used the raw material for producing organic silicon compound, it is also the basic raw material of production polysilicon. In organic synthesis. Trichlorosilane is used in process of hydrosilylation. It is also used for reductive hydrazination which is a high yielding method for preparation of 1,1-disubstituted hydrazines.
  • Production method The method of boiling chlorination Silicon powder after dried is added into boiling chloride furnace, and reacts with dry hydrogen chloride gas which passes into the furnace of at 340 ℃. The generated crude trichlorosilane goes through the wet dust collector, condenser tube and comes into distillation column to separate silicon tetrachloride, trichlorosilane gas from the distillation column is condensed to obtain finished trichlorosilane. Si + 3HCl → SiHCl3 + H2
Technology Process of Trichlorosilane

There total 118 articles about Trichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
In neat (no solvent); SiCl4 reacted with H2 in thermo-plasma at 50 kW at 3500-5000 K;
DOI:10.1134/S0020168510030076
Guidance literature:
copper(l) chloride; at 525 ℃; Product distribution / selectivity;
Refernces Edit

Enantioselective synthesis of 1,2-diarylaziridines by the organocatalytic reductive amination of α-chloroketones

10.1002/anie.200700165

The research explores a new and practical method for synthesizing enantiopure 1,2-diarylaziridines, which are significant in natural products and have potential applications as pesticides with low mammalian toxicity. The study leverages the enantioselective reductive amination of α-chloroketones using trichlorosilane (Cl3SiH) catalyzed by formamides derived from L-valine. Trichlorosilane (Cl3SiH) plays a crucial role as the reducing agent for the enantioselective reductive amination of α-chloroketones. It is used to selectively reduce α-chloroimines to α-chloroamines, which are then cyclized to form the desired aziridines. The use of trichlorosilane in this context is innovative because it allows for high enantioselectivity (up to 96% ee) in the reduction step, which is catalyzed by formamides derived from L-valine. This reduction process is key to achieving the enantiopure α-chloroamines that are essential for the subsequent synthesis of enantiopure 1,2-diarylaziridines. The study highlights the efficiency and selectivity of trichlorosilane in this catalytic reduction, contributing to the overall practicality and novelty of the synthetic method described. It successfully synthesizes 1,2-diarylaziridines as pure enantiomers for the first time, overcoming previous challenges in enantioselective synthesis of these compounds.

Enantioselective conjugate hydrosilylation of α,β-unsaturated ketones

10.1039/c9ra01180c

The research focuses on the enantioselective conjugate hydrosilylation of β,β-disubstituted α,β-unsaturated ketones, utilizing chiral picolinamide–sulfonate Lewis base catalysts. The main objective was to synthesize various chiral ketones with a chiral center at the β-position, which are crucial intermediates for natural products and chiral drugs. The experiments involved screening different chiral Lewis base catalysts for the hydrosilylation of (E)-1,3-diphenylbut-2-en-1-one in acetonitrile at 0°C, and optimizing reaction conditions such as solvents and temperature to achieve the best yield and enantioselectivity. The reactants included α,β-unsaturated ketones, trichlorosilane, and the selected catalyst 2f. The analyses used to determine the success of the reactions and the enantiomeric excess (ee) of the products were chiral high-performance liquid chromatography (HPLC) and nuclear magnetic resonance (NMR) spectroscopy.

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