(4,6-Dimorpholin-4-yl-1,3,5-triazin-2-yl)hydrazine

Base Information

• Chemical Name: (4,6-Dimorpholin-4-yl-1,3,5-triazin-2-yl)hydrazine
• CAS No.: 13017-47-5
• Molecular Formula: C11H19 N7 O2
• Molecular Weight: 281.318
• Hs Code.: 2934999090
• NSC Number: 80865
• DSSTox Substance ID: DTXSID40292220
• Nikkaji Number: J2.714.057B
• Wikidata: Q82030440
• Mol file: 13017-47-5.mol

Synonyms:13017-47-5;(4,6-dimorpholin-4-yl-1,3,5-triazin-2-yl)hydrazine;4,4'-(6-hydrazinyl-1,3,5-triazine-2,4-diyl)dimorpholine;1-(4,6-dimorpholino-1,3,5-triazin-2-yl)hydrazine;STK092848;(2E)-2-hydrazinylidene-4,6-di(morpholin-4-yl)-1,2-dihydro-1,3,5-triazine;NSC80865;Cambridge id 5551381;Oprea1_153735;Oprea1_433359;SCHEMBL1443735;DTXSID40292220;HMS1672J05;NSC-80865;STK742991;AKOS000287664;AKOS000540741;CS-0334537;2-hydrazinyl-4,6-di(morpholin-4-yl)-1,3,5-triazine;2-HYDRAZINYL-4,6-BIS(MORPHOLIN-4-YL)-1,3,5-TRIAZINE

Chemical Property of (4,6-Dimorpholin-4-yl-1,3,5-triazin-2-yl)hydrazine

Chemical Property:

• Vapor Pressure: 5.32E-12mmHg at 25°C
• Boiling Point: 546.6°Cat760mmHg
• Flash Point: 284.3°C
• PSA: 101.66000
• Density: 1.39g/cm³
• LogP: -0.26630
• XLogP3: -0.3
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 3
• Exact Mass: 281.16002287
• Heavy Atom Count: 20
• Complexity: 271

Purity/Quality:

99% ^*data from raw suppliers

4,4'-(6-Hydrazinyl-1,3,5-triazine-2,4-diyl)dimorpholine 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1COCCN1C2=NC(=NC(=N2)NN)N3CCOCC3

Technology Process of (4,6-Dimorpholin-4-yl-1,3,5-triazin-2-yl)hydrazine

There total 4 articles about (4,6-Dimorpholin-4-yl-1,3,5-triazin-2-yl)hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-chloro-4,6-di-morpholin-4-yl-[1,3,5]triazine (7597-22-0) → 4,4’-(6-hydrazineyl-1,3,5-triazine-2,4-diyl)dimorpholine (13017-47-5)

Guidance literature:

With hydrazine; In ethanol; for 3h; Heating / reflux;

Reference yield:

2,6-Dichloro-4-morpholino-1,3,5-triazine (6601-22-5) → 4,4’-(6-hydrazineyl-1,3,5-triazine-2,4-diyl)dimorpholine (13017-47-5)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydrogencarbonate / acetone; water / 24 h / 20 °C

2: hydrazine hydrate / ethanol / 60 °C / Sonication

With sodium hydrogencarbonate; hydrazine hydrate; In ethanol; water; acetone;

DOI:10.1016/j.bioorg.2019.03.063

Reference yield:

(4,6-dimorpholino-1,3,5-triazin-2-yl)trimethylammonium chloride → 4,4’-(6-hydrazineyl-1,3,5-triazine-2,4-diyl)dimorpholine (13017-47-5)

Guidance literature:

With hydrazine hydrate hydrochloride; Basic conditions;

DOI:10.1016/j.tetlet.2009.03.054

upstream raw materials:

2-chloro-4,6-di-morpholin-4-yl-[1,3,5]triazine

2,6-Dichloro-4-morpholino-1,3,5-triazine

Downstream raw materials:

[4-(4,6-Di-morpholin-4-yl-[1,3,5]triazin-2-ylazo)-3-methyl-phenyl]-dimethyl-amine

[4-(4,6-Di-morpholin-4-yl-[1,3,5]triazin-2-ylazo)-phenyl]-dimethyl-amine

C₂₇H₂₉N₇O₃

C₂₁H₂₉N₇O₅