(Z)-1,4-Bis(methoxycarbonyloxy)-2-butene

Base Information

Chemical Name:(Z)-1,4-Bis(methoxycarbonyloxy)-2-butene
CAS No.:5332-81-0
Molecular Formula:C8H12O6
Molecular Weight:204.1773
Hs Code.:
NSC Number:561
DSSTox Substance ID:DTXSID30417748
Nikkaji Number:J322.781B

Synonyms:NSC561;5332-81-0;CARBONIC ACID,4-DIOL;SCHEMBL3454631;DTXSID30417748;NSC-561;But-2-ene-1,4-diyl dimethyl biscarbonate;(Z)-1,4-Bis(methoxycarbonyloxy)-2-butene

Suppliers and Price of (Z)-1,4-Bis(methoxycarbonyloxy)-2-butene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of (Z)-1,4-Bis(methoxycarbonyloxy)-2-butene

Chemical Property:

Vapor Pressure:0.025mmHg at 25°C
Boiling Point:247.9°Cat760mmHg
Flash Point:102.3°C
Density:1.174g/cm³
XLogP3:1.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:8
Exact Mass:204.06338810
Heavy Atom Count:14
Complexity:188

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)OCC=CCOC(=O)OC
Isomeric SMILES:COC(=O)OC/C=C\COC(=O)OC

Technology Process of (Z)-1,4-Bis(methoxycarbonyloxy)-2-butene

There total 1 articles about (Z)-1,4-Bis(methoxycarbonyloxy)-2-butene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

: 6117-80-2
1,4-butenediol

: 616-38-6
carbonic acid dimethyl ester

: 1708-29-8
2,5-dihydrofuran

: 5332-81-0,99260-79-4
carbonic acid (Z)-4-methoxycarbonyloxy-but-2-enyl ester methyl ester

: 140439-75-4,133286-46-1
(Z)-4-hydroxybut-2-en-1-yl methyl carbonate

Guidance literature:: With sodium methylate; for 2h; Reflux; Inert atmosphere;
DOI:10.1002/cssc.201100755

Reference yield: 83.0%

: C₁₇H₁₂BrNO

: 5332-81-0,99260-79-4
carbonic acid (Z)-4-methoxycarbonyloxy-but-2-enyl ester methyl ester

: C₂₁H₁₆BrNO

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In tetrahydrofuran; at 25 ℃; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.9b01060

Reference yield: 83.0%

: C₁₇H₁₂ClNO

: 5332-81-0,99260-79-4
carbonic acid (Z)-4-methoxycarbonyloxy-but-2-enyl ester methyl ester

: C₂₁H₁₆ClNO

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In tetrahydrofuran; at 25 ℃; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.9b01060