Bis(acetonitrile)palladium(II) Dichloride

Base Information

• Chemical Name: Bis(acetonitrile)palladium(II) Dichloride
• CAS No.: 14592-56-4
• Molecular Formula: C₄H₆Cl₂N₂Pd
• Molecular Weight: 259.431
• Hs Code.: 28439090
• Mol file: 14592-56-4.mol

Synonyms:Bis(acetonitrile)palladium(II) Dichloride;Bis(acetonitrile)dichloropalladium(II);Bis(acetonitrile)palladium(II) chloride;acetonitrile;dichloropalladium;MFCD00013122;PdCl2(MeCN)2;Bis(acetonitrile)palladium(ii)chloride;Dichlorobis(acetonitrile)palladium(II);bis(acetonitrile)palladium(II)dichloride;bis(acetonitrile)-palladium(ii) chloride;Bis(acetonitrile)palladium (II) chloride;Pd(MeCN)2Cl2;PdCl2(CH3CN)2;SCHEMBL64732;dichloropalladium bisacetonitrile;dichlorobis(acetonitrile)palladium;RBYGDVHOECIAFC-UHFFFAOYSA-L;Bis(acetonitrile)dichloro-palladium;bis(acetonitrile)palladium chloride;STR02737;bis (acetonitrile) palladium chloride;bis(chloranyl)palladium;ethanenitrile;AKOS015964035;bis(acetonitril)palladium(II) chloride;AC-4985;bis(acetonitrile)dichloro-palladium(II);bisacetonitrile palladium (II) chloride;dichlorobis(acetonitrile)-palladium(II);GC10029;bis-(acetonitrile)palladium(II) chloride;dichloropalladium (II) bis(acetonitrile);SY009905;bis(acetonitrile) palladium (II) chloride;bis(acetonitrile) palladium (II)dichloride;palladium (II) chloride bis(acetonitrile);bis(acetonitrile) palladium (II) dichloride;bis-(acetonitrile) palladium (II) chloride;palladium (II) dichloride bis(acetonitrile);Bis(acetonitrile)dichloropalladium(II), 99%;FT-0624705;DICHLOROBIS(ACETONITRILE)PALLADIUM(III);palladium(2+) ion bis(acetonitrile) dichloride;Bis(acetonitrile)dichloropalladium(II), 99.99%;A808427

Chemical Property of Bis(acetonitrile)palladium(II) Dichloride

Chemical Property:

• Appearance/Colour: dark yellow powder
• Melting Point: 300 °C
• Boiling Point: 63.5 °C at 760 mmHg
• Flash Point: 5.6 °C
• PSA: 47.58000
• LogP: 2.43876
• Storage Temp.: Room temperature.
• Solubility.: Soluble in acetonitrile, acetone, chloroform
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 257.89428
• Heavy Atom Count: 9
• Complexity: 32.1

Purity/Quality:

99% ^*data from raw suppliers

Bis(acetonitrile)dichloropalladium(II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,Xn
• Hazard Codes: T,Xn
• Statements: 23/24/25-36/37/38-20/21/22
• Safety Statements: 16-27-36/37-45-36-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC#N.CC#N.Cl[Pd]Cl
• Uses: suzuki reaction It is used as a catalyst in an ether-directed aza-Claisen rearrangement. Also used in cyclization and cross-coupling reactions. It is applied for olefin isomerization, preparation of acetals and hemiacetal esters. Catalyst used in an ether-directed aza-Claisen rearrangement.

Technology Process of Bis(acetonitrile)palladium(II) Dichloride

There total 26 articles about Bis(acetonitrile)palladium(II) Dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

acetonitrile (75-05-8,26809-02-9) + palladium dichloride → dichloro bis(acetonitrile) palladium(II) (21264-30-2,90243-59-7,14592-56-4)

Guidance literature:

for 3h; Inert atmosphere; Reflux;

DOI:10.1021/acs.orglett.5b00987

Reference yield: 91.0%

palladium (7440-05-3) + acetonitrile (75-05-8,26809-02-9) → dichloro bis(acetonitrile) palladium(II) (21264-30-2,90243-59-7,14592-56-4)

Guidance literature:

With Oxone; In neat (no solvent); at 20 ℃; Milling;

DOI:10.1002/anie.201712602

Reference yield:

[(N-butyronitrile pyridinium)2PdCl2][BF4]2 + acetonitrile (75-05-8,26809-02-9) → dichloro bis(acetonitrile) palladium(II) (21264-30-2,90243-59-7,14592-56-4)

Guidance literature:

In acetonitrile;

DOI:10.1021/ja0463482

upstream raw materials:

bis(triphenylphosphine)platinum(II) dichloride

acetonitrile

dichloro(cycloocta-1,5-diene)palladium (II)

cis-[PdCl₂(tri(methylallyl)arsine)2]

Downstream raw materials:

palladium(II) tetraphenylporphyrin

cis-[PdCl₂(P(OC₆H₃-3,5-Me₂)3)2]

Refernces

• 1、 Khisamutdinov,Shitikova,Anpilogova,Golubyatnikova,Mulagaleev,Murinov. "Palladium(II) chloro complexes with (RS)-1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol". . p. 638 - 646. Retrieved 2015.
• 2、 Sanz, Corey A.,Ferguson, Michael J.,McDonald, Robert,Patrick, Brian O.,Hicks, Robin G.. "Classical and non-classical redox reactions of Pd(ii) complexes containing redox-active ligands". . p. 11676 - 11678. Retrieved 2014.
• 3、 Gusevskaya,Beck,Stepanov,Likholobov,Nekipelov,Yermakov,Zamaraev. "STUDY ON THE MECHANISM OF ETHYLENE OXIDATION BY A NITRITE COMPLEX OF PALLADIUM IN CHLOROFORM MEDIUM.". . p. 177 - 188. Retrieved 1986.
• 4、 Mathews, Christopher J.,Smith, Paul J.,Welton, Tom. "N-donor complexes of palladium as catalysts for Suzuki cross-coupling reactions in ionic liquids". . p. 27 - 32. Retrieved 2004.
• 5、 Luu, Hieu-Trinh,Wiesler, Stefan,Frey, Georg,Streuff, Jan. "A Titanium(III)-Catalyzed Reductive Umpolung Reaction for the Synthesis of 1,1-Disubstituted Tetrahydroisoquinolines". . p. 2478 - 2481. Retrieved 2015.
• 6、 Basova, Tamara V.,Kovaleva, Evgenia A.,Krasnov, Pavel O.,Morozova, Natalya B.,Nikolaeva, Nataliya S.,Smolentsev, Anton I.,Sukhikh, Alexander A.,Vikulova, Evgeniia S.. "Synthesis, structural, vibrational and DFT investigation of new binuclear molecular Pd–Cu and Cu–Cu complexes formed by Schiff base and hexafluoroacetylacetonate building blocks". . . Retrieved 2020.
• 7、 Vikulova, Evgeniia S.,Cherkasov, Sergey A.,Nikolaeva, Nataliya S.,Smolentsev, Anton I.,Sysoev, Sergey V.,Morozova, Natalya B.. "Thermal behavior of volatile palladium(II) complexes with tetradentate Schiff bases containing propylene-diimine bridge". . p. 1 - 10. Retrieved 2018.
• 8、 Al-Azmi, Amal. "Synthesis, crystal analysis and DFT calculations of Ni(II) and Pd(II) complexes of 3,3'-((1,2-phenylenebis(azanediyl))bis(2-oxoethane-2,1-diyl))bis(1-allyl-1H-imidazole-3-ium)". . p. 179 - 187. Retrieved 2019.
• 9、 Hossain, A. G. M. Mostafa,Nagaoka,Ogura. "Electrocatalytic reduction of carbon dioxide by substituted pyridine and pyrazole complexes of palladium". . p. 2773 - 2780. Retrieved 1996.
• 10、 Bakir, Mohammed,Lawrence, Mark W.,Nelson, Peter,Yamin, M. Bohari. "Catalytic C–C cross-coupling and hydrogen evolution by two Pd(II)-complexes of di-2-pyridyl ketone benzoyl hydrazones". . p. 2261 - 2278. Retrieved 2019.