Dichlorobis(1,1'-thiobis(benzene))platinum

Base Information

Chemical Name:Dichlorobis(1,1'-thiobis(benzene))platinum
CAS No.:50525-38-7
Molecular Formula:C₂₄H₂₀Cl₂PtS₂
Molecular Weight:638.541
Hs Code.:
European Community (EC) Number:256-612-5
Mol file:50525-38-7.mol

Synonyms:EINECS 256-612-5;Dichlorobis(1,1'-thiobis(benzene))platinum;NSC 173336;50525-38-7;C24H20Cl2PtS2;C24-H20-Cl2-Pt-S2;dichlorobis[1,1'-thiobis[benzene]]platinum;S(c1ccccc1)(c2ccccc2)[Pt](Cl)(Cl)S(c3ccccc3)c4ccccc4

Suppliers and Price of Dichlorobis(1,1'-thiobis(benzene))platinum

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Dichlorobis(1,1'-thiobis(benzene))platinum

Chemical Property:

Melting Point:195 °C
PSA：77.60000
LogP:8.51670
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:639.018793
Heavy Atom Count:29
Complexity:296

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[SH+]C2=CC=CC=C2.C1=CC=C(C=C1)[SH+]C2=CC=CC=C2.Cl[Pt]Cl

Technology Process of Dichlorobis(1,1'-thiobis(benzene))platinum

There total 3 articles about Dichlorobis(1,1'-thiobis(benzene))platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 50525-38-7,17611-28-8,21710-19-0
dichlorobis(diphenyl sulfide)platinum(II)

: 17611-28-8,21710-19-0,50525-38-7
cis-dichlorobis(diphenyl sulfide)platinum(II)

Guidance literature:: With (C₆H₅)3SnH; In benzene; addn. of a soln. of Ph3SnH in benzene to PtCl2(SPh2)2 in benzene, mixt. stirred overnight; filtered, filtrate evapd. to dryness, residue dissolved in CH2Cl2/benzene and MeOH, soln. filtered, crystn. from filtrate;
DOI:10.1107/S010827010100960X

Reference yield:

: 10025-99-7
potassium tetrachloroplatinate(II)

: 139-66-2
diphenyl sulfide

: 17611-28-8,21710-19-0,50525-38-7
cis-dichlorobis(diphenyl sulfide)platinum(II)

Guidance literature:: In ethanol; water; shaking an aq. soln. of K2(PtCl4) with an equivalent amount of S(C6H5)2 in alcohol for 24 h; shaking with further alcohol;; washing with H2O; drying in air; recrystallization from C6H6 or from a mixture of alcohol and CHCl3 (1:1);;

Reference yield:

: 50525-38-7,17611-28-8,21710-19-0
dichlorobis(diphenyl sulfide)platinum(II)

: 21710-19-0,17611-28-8,50525-38-7
trans-dichlorobis(diphenyl sulfide)platinum(II)

Guidance literature:: With SnCl₂; In acetone; addn. of SnCl2 to PtCl2(SPh2)2 in acetone, soln. was left overnight; filtered, crystn. by slow evapn. of filtrate;
DOI:10.1107/S010827010100960X