1,4-Dimethoxyphenazine

Base Information

• Chemical Name: 1,4-Dimethoxyphenazine
• CAS No.: 13860-45-2
• Molecular Formula: C14H12N2O2
• Molecular Weight: 240.2573
• NSC Number: 156944
• DSSTox Substance ID: DTXSID40303143
• Wikidata: Q82048288
• ChEMBL ID: CHEMBL1802265
• Mol file: 13860-45-2.mol

Synonyms:1,4-dimethoxyphenazine;13860-45-2;CHEMBL1802265;NSC156944;DTXSID40303143;BDBM50347477;NSC-156944

Chemical Property of 1,4-Dimethoxyphenazine

Chemical Property:

• Vapor Pressure: 2.3E-07mmHg at 25°C
• Boiling Point: 435°Cat760mmHg
• Flash Point: 156.7°C
• Density: 1.25g/cm³
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 240.089877630
• Heavy Atom Count: 18
• Complexity: 259

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C2=NC3=CC=CC=C3N=C12)OC

Technology Process of 1,4-Dimethoxyphenazine

There total 8 articles about 1,4-Dimethoxyphenazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 1,4-Dimethoxy-phenazin (13860-45-2)

Guidance literature:

With iron; paraffin oil;

DOI:10.1038/160437a0

Reference yield:

ortoquinone (583-63-1) + 2,3-diamino-1,4-dimethoxybenzene (40328-95-8) → 1,4-Dimethoxy-phenazin (13860-45-2)

Guidance literature:

With acetic acid; In benzene; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1021/jm1011066

Reference yield:

nitrobenzene (98-95-3,26969-40-4) + 2,5-dimethoxyaniline (102-56-7,102526-87-4) → 1,4-Dimethoxy-phenazin (13860-45-2)

Guidance literature:

With potassium hydroxide; In toluene; at 90 ℃; for 16h;

DOI:10.1039/d1ta03655f

upstream raw materials:

6,9-dimethoxy-1,2,3,4-tetrahydro-phenazine

nitrobenzene

2,5-dimethoxyaniline

1,4-dimethoxy-2-nitrobenzene

Refernces

• 1、 Wellala, Nadeesha P. N.,Hollas, Aaron,Duanmu, Kaining,Murugesan, Vijayakumar,Zhang, Xin,Feng, Ruozhu,Shao, Yuyan,Wang, Wei. "Decomposition pathways and mitigation strategies for highly-stable hydroxyphenazine flow battery anolytes". . p. 21918 - 21928. Retrieved 2021/10/12.