Dilithium;pentane

Base Information

• Chemical Name: Dilithium;pentane
• CAS No.: 2223-58-7
• Molecular Formula: C5H10 Li2
• Molecular Weight: 84.0164
• European Community (EC) Number: 218-738-9

Synonyms:C5H10Li2;C5-H10-Li2;2223-58-7

Chemical Property of Dilithium;pentane

Chemical Property:

• Boiling Point: 35.2°Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 86.12590725
• Heavy Atom Count: 7
• Complexity: 7.5

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Li+].[Li+].CCCCC

Technology Process of Dilithium;pentane

There total 2 articles about Dilithium;pentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,5-dibromo-pentane (111-24-0) → 1,5-Dilithiopentane (2223-58-7)

Guidance literature:

With lithium;

DOI:10.1021/ja01652a036 DOI:10.1007/BF00609361

Reference yield:

1,5-diiodopentane (628-77-3) → 1,5-Dilithiopentane (2223-58-7)

Guidance literature:

With tert.-butyl lithium; In pentane; 1)-78 deg C, 0.5-1h, 2) warmed to 23 deg C in 0.5-1h;

DOI:10.1021/jo00306a022

Reference yield: 70.0%

chloro-trimethyl-silane (75-77-4) + 1,5-Dilithiopentane (2223-58-7) → 1,5-Bis-trimethylsilyl-pentan (15895-92-8)

Guidance literature:

DOI:10.1021/jo00306a022

upstream raw materials:

1,5-dibromo-pentane

1,5-diiodopentane

Downstream raw materials:

1,5-Bis-trimethylsilyl-pentan

1,1-diphenyl-silinane

hexa-Si-phenyl-Si,Si'-pentanediyl-bis-silane

1,1-dimethyl-1-silacyclohexane

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