Phosphinothioic acid, (1,1-dimethylethyl)phenyl-, S-methyl ester, (R)-

Base Information

Chemical Name:Phosphinothioic acid, (1,1-dimethylethyl)phenyl-, S-methyl ester, (R)-
CAS No.:51584-29-3
Molecular Formula:C11H17OPS
Molecular Weight:228.2908
Hs Code.:
DSSTox Substance ID:DTXSID60965909
Wikidata:Q82948233

Synonyms:51584-29-3;Phosphinothioic acid, (1,1-dimethylethyl)phenyl-, S-methyl ester, (R)-;DTXSID60965909;S-methyl tert-butyl(phenyl)phosphinothioate

Suppliers and Price of Phosphinothioic acid, (1,1-dimethylethyl)phenyl-, S-methyl ester, (R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Phosphinothioic acid, (1,1-dimethylethyl)phenyl-, S-methyl ester, (R)-

Chemical Property:

Vapor Pressure:0.001mmHg at 25°C
Boiling Point:315.6°Cat760mmHg
Flash Point:144.6°C
Density:1.07g/cm³
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:228.07377333
Heavy Atom Count:14
Complexity:226

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)P(=O)(C1=CC=CC=C1)SC
Isomeric SMILES:CC(C)(C)[P@@](=O)(C1=CC=CC=C1)SC

Technology Process of Phosphinothioic acid, (1,1-dimethylethyl)phenyl-, S-methyl ester, (R)-

There total 3 articles about Phosphinothioic acid, (1,1-dimethylethyl)phenyl-, S-methyl ester, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 54100-47-9
(R)-(+)-tert-butylphenylphosphanylthioic acid

: 74-88-4
methyl iodide

: 51584-29-3,51584-30-6,76380-86-4
S-methyl tert-(butylphenylphosphino)thiolate

Guidance literature:: With triethylamine; In benzene; for 33h;

Reference yield: 80.0%

: 594-19-4
tert.-butyl lithium

: C₁₆H₂₁OPS₂

: 74-88-4
methyl iodide

: 51584-29-3
(R)-(+)-S-methyl tert-butylphenylphosphinothiolate

Guidance literature:: tert.-butyl lithium; C₁₆H₂₁OPS₂; In tetrahydrofuran; at -78 ℃; for 3h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; at -78 - 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jacs.9b13898