Einecs 237-023-2

Base Information

• Chemical Name: Einecs 237-023-2
• CAS No.: 13587-51-4
• Molecular Formula: HSi
• Molecular Weight: 33.1093
• European Community (EC) Number: 237-023-2
• DSSTox Substance ID: DTXSID20929163
• Wikidata: Q76324290
• Mol file: 13587-51-4.mol

Synonyms:EINECS 237-023-2;13587-51-4;[2H]silane;(2H)Silane;deuterosilane;DH3Si;(~2~H_1_)Silane;D-H3-Si;DTXSID20929163

Chemical Property of Einecs 237-023-2

Chemical Property:

• Vapor Pressure: 54300mmHg at 25°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 29.991028312
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [SiH]
• Isomeric SMILES: [2H][Si]

Technology Process of Einecs 237-023-2

There total 11 articles about Einecs 237-023-2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

silanium cation (41753-67-7) + Dipropyl ether (111-43-3) → silane (13587-51-4) + H3SiOC3H7 + HSiC3H7 + silacarbene (7440-21-3)

Guidance literature:

byproducts: (n-Pr)2OH(1+), C3H7(1+), C3H7OC3H6(1+); Fourier transform ion cyclotron resonance spectrometer (total pressure (1-2)E-6 Torr, electron energy 14 eV); Fourier transform ion cyclotron resonance spectroscopy; Kinetics;

DOI:10.1021/j100399a009

Reference yield:

disilane (1590-87-0) + deuterium (16873-17-9,12184-84-8) → silyl (7440-21-3) + silane (13587-51-4) + disilyl radical (73151-72-1,1590-87-0) + deuterium hydride

Guidance literature:

In gas; D atoms were generated by Hg-sensitized photolysis of D2; ratio of rate consts. for substitution D + Si2H6 -> SiH3D + SiH3 and abstraction D + Si2H6 -> HD + Si2H5 was detd. by stationary photolysis (measuring the product ratio SiH3D/HD); reaction products were analyzed by mass spectrometry and by gas chromy.; Kinetics;

DOI:10.1021/om00137a030

Reference yield:

lithium aluminium deuteride + iodosilane (13598-42-0) → silane (13587-51-4)

Guidance literature:

In dibutyl ether; byproducts: SiH4; purifn. by high vac. techniques; only traces of SiH4 as impurity;

DOI:10.1016/0022-2852(86)90077-9

upstream raw materials:

⁽²⁾H₃Si⁽¹⁺⁾

monosilane

H⁽²⁾H₂Si⁽¹⁺⁾

H₂⁽²⁾HSi⁽¹⁺⁾

Refernces

• 1、 Fabry,Potzinger,Reimann,Ritter,Steenbergen. "Gas-phase homolytic substitution reactions of hydrogen atoms at silicon centers". . p. 1231 - 1235. Retrieved 1986.
• 2、 Reents, W. D.,Mandich, M. L.. "H/D isotope exchange reaction of SiH3+ with SiD4 and SiD3+ with SiH4: Evidence for hydride stripping reaction". . p. 3270 - 3276. Retrieved 2007/10/02.