Diiodo(diphenyl)plumbane

Base Information

• Chemical Name: Diiodo(diphenyl)plumbane
• CAS No.: 23351-01-1
• Molecular Formula: C₁₂H₁₀I₂Pb
• Molecular Weight: 615.22
• NSC Number: 53719
• DSSTox Substance ID: DTXSID00287975
• Mol file: 23351-01-1.mol

Synonyms:diiodo(diphenyl)plumbane;23351-01-1;NSC53719;diphenyllead diiodide;DIIODODIPHENYLLEAD;SCHEMBL3144793;DTXSID00287975;NSC-53719;AKOS024432754

Chemical Property of Diiodo(diphenyl)plumbane

Chemical Property:

• Vapor Pressure: 4.05E-07mmHg at 25°C
• Boiling Point: 427.5°Cat760mmHg
• Flash Point: 212.4°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 615.86385
• Heavy Atom Count: 15
• Complexity: 174

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Pb](C2=CC=CC=C2)(I)I

Technology Process of Diiodo(diphenyl)plumbane

There total 1 articles about Diiodo(diphenyl)plumbane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iodine (7553-56-2,12190-71-5,8031-47-8) + Tetraphenyllead (595-89-1) → diphenyldiiodoplumbane (23351-01-1)

Guidance literature:

In chloroform; soln. of I2 in CHCl3 added dropwise to soln. of Pb(C6H5)4 in CHCl3; concd., petroleum spirits added;

DOI:10.1016/j.jorganchem.2007.07.010

Reference yield: 90.0%

diphenyldiiodoplumbane (23351-01-1) + m-tolylmagnesium bromide (28987-79-3) → (C6H5)2Pb(C6H4CH3)2

Guidance literature:

In tetrahydrofuran; room temp. (2 h), refluxing (12 h); recrystn. (EtOH); elem. anal.;

DOI:10.1016/S0277-5387(98)00256-3

Reference yield: 78.0%

diphenyldiiodoplumbane (23351-01-1) + K(1+)*(C6H5CH2)2POCS2(1-)=K(C6H5CH2)2POCS2 (330476-37-4) → Pb(C6H5)2I((C6H5CH2)2POCS2)

Guidance literature:

In acetone; byproducts: KBr; Pb-complex was added to suspn. of ligand in acetone, stirred for 2 min; centrifuged, 2-propanol was added, kept at -5°C overnight, filtered, washed with 2-propanol, dried in vacuo; elem. anal.;

DOI:10.1039/b006672i

upstream raw materials:

iodine

Tetraphenyllead

Downstream raw materials:

2,2-diphenyl-1,3,6,2-trithiaplumbocane

diiododiphenylbis(o-methoxyphenylthiourea)lead(IV)

diiododiphenylbis(o-hydroxyphenylthiourea)lead(IV)

diiododiphenylbis(o-tolylthiourea)lead(IV)