Cyanogen fluoride

Base Information

• Chemical Name: Cyanogen fluoride
• CAS No.: 1495-50-7
• Molecular Formula: CF N
• Molecular Weight: 45.0161
• DSSTox Substance ID: DTXSID20164330
• Nikkaji Number: J566E
• Wikipedia: Cyanogen_fluoride
• Wikidata: Q5197465
• Mol file: 1495-50-7.mol

Synonyms:carbononitridic fluoride;cyanogen fluoride

Chemical Property of Cyanogen fluoride

Chemical Property:

• Vapor Pressure: 5300mmHg at 25°C
• Melting Point: -82°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 23.79000
• Density: 1.026g/cm³
• LogP: 0.43698
• Water Solubility.: insoluble H2O [HAW93]
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 45.001477166
• Heavy Atom Count: 3
• Complexity: 31.3

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(#N)F

Technology Process of Cyanogen fluoride

There total 45 articles about Cyanogen fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tetracyanomethane (24331-09-7) + cesium fluoride (13400-13-0) → Cs(1+)*C(CN)3(1-)=CsC{CN}3 + cyanogen fluoride (1495-50-7)

Guidance literature:

In not given; in shaker, ambient temp.; evapn. formed FCN condensed by liquid N2;

Reference yield: 50.0%

trifluoro-[1,3,5]triazine (675-14-9) → cyanogen fluoride (1495-50-7)

Guidance literature:

In not given; pyrolysis at 1300-1400°C, in N2, at 50 Torr;

DOI:10.1021/ja01067a011

Reference yield: 30.0%

ethanedinitrile (460-19-5,25215-76-3) + trifluoroacetonitrile (353-85-5) → cyanogen fluoride (1495-50-7)

Guidance literature:

In not given; in arc-light plasma;

DOI:10.1021/ja01067a011

upstream raw materials:

trifluoro-[1,3,5]triazine

difluoro-methylene

thiocyanogen

azidotrifluoromethane

Downstream raw materials:

cyanogen azide

trifluoro-[1,3,5]triazine

carbon tetrafluoride

perfluoromethanimine

Refernces

• 1、 Fawcett,Libscomb. "-". . p. 1509,1510. Retrieved 1960.
• 2、 Hynes,Austin,Bigelow. "Chemistry of fluorinated derivatives of azodiformamidine". . p. 418 - 420. Retrieved 1972.
• 3、 Jacobs, Juergen,Juelicher, Bernd,Schatte, Gabriele,Willner, Helge,Mack, Hans-Georg. "CFNO-Isomers - Theoretical and Experimental Studies". . p. 2167 - 2176. Retrieved 2007/10/02.
• 4、 Tsai, Cheng-ping,McFadden, David L.. "Gas-Phase Atom-Radical Kinetics of Atomic Hydrogen, Nitrogen, and Oxygen Reactions with CHF Radicals.". . p. 3298 - 3300. Retrieved 2007/10/02.