Manganese, tricarbonyl((1,2,3,4,5-eta5)-2,4-cycloheptadien-1-yl)-

Base Information

Chemical Name:Manganese, tricarbonyl((1,2,3,4,5-eta5)-2,4-cycloheptadien-1-yl)-
CAS No.:32798-86-0
Molecular Formula:C₁₀H₉MnO₃
Molecular Weight:232.118
Hs Code.:

Synonyms:

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Chemical Property of Manganese, tricarbonyl((1,2,3,4,5-eta5)-2,4-cycloheptadien-1-yl)-

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of Manganese, tricarbonyl((1,2,3,4,5-eta5)-2,4-cycloheptadien-1-yl)-

There total 2 articles about Manganese, tricarbonyl((1,2,3,4,5-eta5)-2,4-cycloheptadien-1-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 13985-77-8
phenylpentacarbonylmanganese(I)

: 544-25-2
Cyclohepta-1,3,5-triene

: 10170-69-1
dimanganese decacarbonyl

: 32798-86-0
tricarbonyl(η(5)-2,4-cycloheptadien-yl)manganese

: [Mn(1-5-η-C7H8(Ph-6-endo))(CO)3]

Guidance literature:: In n-heptane; N2-atmosphere; refluxing (20 h); solvent removal (reduced pressure), chromy. (Al2O3/light petroleum); elem. anal.;
DOI:10.1039/DT9770000001

Reference yield:

: C₉H₉MnNO₃⁽¹⁺⁾

: 100-58-3
phenylmagnesium bromide

: 32798-86-0
tricarbonyl(η(5)-2,4-cycloheptadien-yl)manganese

: C₇H₉C₆H₅Mn(CO)2(NO)

Guidance literature:: In diethyl ether; a slight excess of PhMgBr was added to a soln. (or a susp.) of the complex under N2 and stirred at room temp.; not isolated, identified by IR spectrum;
DOI:10.1039/c39860000691

Reference yield: 95.0%

: 32798-86-0
tricarbonyl(η(5)-2,4-cycloheptadien-yl)manganese

: 591-51-5
phenyllithium

: {Mn(CO)2(C(O)Ph)(η5-C7H9)}{Li(Et2O)2}

Guidance literature:: In diethyl ether; under dry N2, Standard Schlenk techniques; dropwise addn. by syringe of PhLi to a stirred soln. of the Mn-compd. in diethyl ether at room temp.; pptn. upon partial removal of the solvent in vac., removal of the remaining mother liquor via cannula, washing with n-hexane and drying in vac.; elem. anal.;
DOI:10.1021/ja00062a025