Manganese, phenyl pentacarbonyl

Base Information

• Chemical Name: Manganese, phenyl pentacarbonyl
• CAS No.: 13985-77-8
• Molecular Formula: C11H15MnO5
• Molecular Weight: 272.096
• Mol file: 13985-77-8.mol

Synonyms:CH28432 PENTACARBONYLPHENYLMANGANESE;phenylmanganese pentacarbonyl;

Chemical Property of Manganese, phenyl pentacarbonyl

Chemical Property:

• PSA: 0.00000
• LogP: 0.90130

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Manganese, phenyl pentacarbonyl

There total 8 articles about Manganese, phenyl pentacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

dimanganese decacarbonyl (10170-69-1) + diphenylmercury(II) (587-85-9,1337-09-3) → phenylpentacarbonylmanganese(I) (13985-77-8)

Guidance literature:

In cyclohexane; Irradiation (UV/VIS); 20 h; elem. anal.;

Reference yield: 54.0%

bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5) + I(C6H5)2(1+)*Mn(CO)5(1-)={I(C6H5)2}{Mn(CO)5} (142198-39-8) → pentacarbonylmanganate (35816-56-9,14971-26-7,71564-22-2) + dimanganese decacarbonyl (10170-69-1) + phenylpentacarbonylmanganese(I) (13985-77-8)

Guidance literature:

In tetrahydrofuran; addn. of the solid iodonium salt to a soln. of the Mn-complex in THF at 22°C, stirring for 5 min; monitored by IR;

DOI:10.1016/0022-328X(92)83221-3

Reference yield: 44.0%

bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5) + triphenylsulphonium hexafluorophosphate (57835-99-1) → dimanganese decacarbonyl (10170-69-1) + phenylpentacarbonylmanganese(I) (13985-77-8)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); prepn. of Ph3SMn(CO)5 in situ from PPNMn(CO)5 and Ph3SPF6 in THF in the dark, then irradn. for 30 min; monitored by IR;

DOI:10.1016/0022-328X(92)83221-3

upstream raw materials:

bis(triphenylphosphineiminium) pentacarbonylmanganate^(1-)

diphenyliodonium hexafluorophosphate

triphenylsulphonium hexafluorophosphate

potassium[manganese(pentacarbonyl)]

Downstream raw materials:

tetracarbonyl(η3-1-phenyl-2-penten-4-yl)manganese

dimanganese decacarbonyl

[Mn(1-5-η-C7H8(Me))(CO)3]

tricarbonyl(η(5)-2,4-cycloheptadien-yl)manganese

Refernces

• 1、 Wei, C.-H.,Bockman, T. M.,Kochi, J. K.. "Charge-transfer salts of carbonylmetalates as outer-sphere ion pairs in photochemical and thermal electron transfer". . p. 85 - 97. Retrieved 2007/10/02.
• 2、 Gismondi, Thomas E.,Rausch, Marvin D.. "PHOTO-INDUCED DEGRADATION REACTIONS OF SOME ALKYL- AND ARYL-CARBONYL DERIVATIVES OF MANGANESE, MOLYBDENUM AND TUNGSTEN". . p. 59 - 72. Retrieved 2007/10/02.