Bis(4-tert-butylphenyl) disulfide

Base Information

• Chemical Name: Bis(4-tert-butylphenyl) disulfide
• CAS No.: 7605-48-3
• Molecular Formula: C20H26S2
• Molecular Weight: 330.558
• NSC Number: 677482,158727
• UNII: 9TQJ1AL17F
• DSSTox Substance ID: DTXSID10226951
• Nikkaji Number: J1.638.005I
• Wikidata: Q83106535
• ChEMBL ID: CHEMBL120709
• Mol file: 7605-48-3.mol

Synonyms:7605-48-3;Bis(4-tert-butylphenyl) disulfide;9TQJ1AL17F;1-tert-butyl-4-[(4-tert-butylphenyl)disulfanyl]benzene;UNII-9TQJ1AL17F;NSC 158727;NSC-158727;NSC158727;NSC-677482;4-Tert-butylphenyl disulfide;SCHEMBL916740;bis(4-t-butylphenyl) disulfide;CHEMBL120709;DTXSID10226951;JHJKMOPTKMUFOG-UHFFFAOYSA-N;di-(4-tert-butylphenyl) disulphide;NSC677482;AKOS025296111;DI-4-TERT-BUTYLPHENYL DISULFIDE;BIS(P-TERT-BUTYLPHENYL) DISULFIDE;DISULFIDE, BIS(P-TERT-BUTYLPHENYL);BIS(4-(1,1-DIMETHYLETHYL)PHENYL) DISULFIDE;DISULFIDE, BIS(4-(1,1-DIMETHYLETHYL)PHENYL)

Chemical Property of Bis(4-tert-butylphenyl) disulfide

Chemical Property:

• Boiling Point: 408.4°Cat760mmHg
• Flash Point: 155.2°C
• Density: 1.07g/cm³
• XLogP3: 7.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 330.14759318
• Heavy Atom Count: 22
• Complexity: 287

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)C1=CC=C(C=C1)SSC2=CC=C(C=C2)C(C)(C)C

Technology Process of Bis(4-tert-butylphenyl) disulfide

There total 35 articles about Bis(4-tert-butylphenyl) disulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-t-butylbenzenethiol (2396-68-1) → bis(4-tert-butylphenyl)disulfide (7605-48-3)

Guidance literature:

With (S)-tetrahydrotellurophen-3-amine hydrochloride; dihydrogen peroxide; In dichloromethane; at 25 ℃; pH=7.5; Flow reactor;

DOI:10.1039/c9cy00562e

Reference yield: 96.0%

4-tert-butylbenzenesulfinic acid methyl ester (1264737-41-8) → bis(4-tert-butylphenyl)disulfide (7605-48-3)

Guidance literature:

With hydrazine hydrate; In dimethyl sulfoxide; at 20 ℃; for 18h;

DOI:10.1080/00397911.2010.535947

Reference yield: 92.0%

4-t-butylbenzenethiol (2396-68-1) + cyclopropylboronic acid (411235-57-9) → bis(4-tert-butylphenyl)disulfide (7605-48-3) + (4-(tert-butyl)phenyl)(cyclopropyl)sulfane

Guidance literature:

With [2,2]bipyridinyl; copper diacetate; caesium carbonate; In 1,2-dichloro-ethane; at 70 ℃; for 16h; Reagent/catalyst; Sealed tube;

DOI:10.3762/bjoc.15.113

upstream raw materials:

4-tert-butylbenzenesulfonyl chloride

4-t-butylbenzenethiol

Bis(p-tert-butylphenyl) trisulfide

NaSph-4-Cme₃

Downstream raw materials:

4-t-butylbenzenethiol

4-[2-(4-tert-butylphenylthio)thien-4-yl]-4-methoxytetrahydropyran

Sn(SC₆H₄(t-Bu)-p)4(2,2'-bipyridine)

Sn(SC₆H₄(t-Bu)-p)4(4-picoline)2