S-(4-tert-butylphenyl) 4-tert-butylbenzenesulfonothioate

Base Information

• Chemical Name: S-(4-tert-butylphenyl) 4-tert-butylbenzenesulfonothioate
• CAS No.: 31197-50-9
• Molecular Formula: C20H26 O2 S2
• Molecular Weight: 362.557
• Mol file: 31197-50-9.mol

Synonyms:Benzenesulfonicacid, p-tert-butylthio-, S-(p-tert-butylphenyl) ester (6CI,8CI); NSC 243179

Chemical Property of S-(4-tert-butylphenyl) 4-tert-butylbenzenesulfonothioate

Chemical Property:

• Vapor Pressure: 1.18E-08mmHg at 25°C
• Boiling Point: 472.8°C at 760 mmHg
• Flash Point: 239.7°C
• Density: 1.15g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of S-(4-tert-butylphenyl) 4-tert-butylbenzenesulfonothioate

There total 8 articles about S-(4-tert-butylphenyl) 4-tert-butylbenzenesulfonothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

4-tert-butylbenzene sulfinic acid sodium salt → S-(4-(tert-butyl)phenyl) 4-(tert-butyl)benzenesulfonothioate (31197-50-9)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at 50 ℃; for 3h;

DOI:10.1021/acs.orglett.8b01808

Reference yield: 87.0%

4-(tert-butyl)benzenesulfonyl hydrazide (65604-75-3) → S-(4-(tert-butyl)phenyl) 4-(tert-butyl)benzenesulfonothioate (31197-50-9)

Guidance literature:

With dipotassium peroxodisulfate; N-iodo-succinimide; In tetrahydrofuran; at 70 ℃; for 8h; Schlenk technique; Green chemistry;

DOI:10.1055/s-0037-1610649

Reference yield: 84.0%

4-tert-butylbenzenesulfonyl chloride (15084-51-2) → S-(4-(tert-butyl)phenyl) 4-(tert-butyl)benzenesulfonothioate (31197-50-9)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; In acetone; acetonitrile; at 20 ℃; for 20h; chemoselective reaction;

DOI:10.1002/adsc.201600633

upstream raw materials:

4-tert-butylbenzenesulfonyl chloride

bis(4-tert-butylphenyl)disulfide

4-t-butylbenzenethiol

sodium methansulfinate

Downstream raw materials:

1-tert-butyl-4-[(trifluoromethyl)sulfanyl]benzene

Refernces

• 1、 Zhang, Guofu,Fan, Qiankun,Zhao, Yiyong,Wang, Huimin,Ding, Chengrong. "Dual Roles of Rongalite: Reductive Coupling Reaction to Construct Thiosulfonates Using Sulfonyl Hydrazides". . p. 81 - 85. Retrieved 2020/11/03.
• 2、 Bian, Mouwang,Dai, Lei,Mao, Kaimin,Rong, Liangce,Wang, Chang,Yu, Qiuyu,Zhang, Jinghang. "Metal-Free Radical Annulation of Oxygen-Containing 1,7-Enynes: Configuration-Selective Synthesis of (E)-3-((Arylsulfonyl)methyl)-4-Substituted Arylidenechromene Derivatives". supporting information. p. 218 - 224. Retrieved 2021/01/13.