Ethyl 7-chloro-3-methyl-1-benzofuran-2-carboxylate

Base Information

Chemical Name:Ethyl 7-chloro-3-methyl-1-benzofuran-2-carboxylate
CAS No.:32565-17-6
Molecular Formula:C₁₂H₁₁ClO₃
Molecular Weight:238.671
Hs Code.:2932999099
DSSTox Substance ID:DTXSID60368375
Wikidata:Q82154862
Mol file:32565-17-6.mol

Synonyms:32565-17-6;ethyl 7-chloro-3-methyl-1-benzofuran-2-carboxylate;7-Chloro-3-methyl-benzofuran-2-carboxylic acid ethyl ester;Ethyl 7-chloro-3-methylbenzofuran-2-carboxylate;DTXSID60368375;AKOS000122578;2-carbethoxy-3-methyl-7-chlorobenzofuran;CS-0219784;FT-0764272;EN300-04922;Ethyl7-chloro-3-methylbenzofuran-2-carboxylate;SR-01000039514;J-018784;SR-01000039514-1;Z54083135;ethyl 7-chloro-3-methyl-1-benzo[b]furan-2-carboxylate

Suppliers and Price of Ethyl 7-chloro-3-methyl-1-benzofuran-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
7-CHLORO-3-METHYL-BENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER 95.00%
2.5G
$ 1147.43

American Custom Chemicals Corporation
7-CHLORO-3-METHYL-BENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER 95.00%
1G
$ 729.00

AK Scientific
Ethyl7-chloro-3-methyl-1-benzofuran-2-carboxylate
100mg
$ 189.00

Total 5 raw suppliers

Chemical Property of Ethyl 7-chloro-3-methyl-1-benzofuran-2-carboxylate

Chemical Property:

Vapor Pressure:0.000256mmHg at 25°C
Boiling Point:323.8°Cat760mmHg
Flash Point:149.6°C
PSA：39.44000
Density:1.263g/cm³
LogP:3.57130
XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:238.0396719
Heavy Atom Count:16
Complexity:269

Purity/Quality:

99% ^*data from raw suppliers

7-CHLORO-3-METHYL-BENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1=C(C2=C(O1)C(=CC=C2)Cl)C

Technology Process of Ethyl 7-chloro-3-methyl-1-benzofuran-2-carboxylate

There total 3 articles about Ethyl 7-chloro-3-methyl-1-benzofuran-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 32565-14-3
ethyl 2-(2-chlorophenoxy)-3-oxobutanoate

: 32565-17-6
2-carbethoxy-3-methyl-7-chlorobenzofuran

Guidance literature:: With polyphosphoric acid; at 85 ℃; for 8h;
DOI:10.1134/S0012500818100051

Reference yield:

: 2009-97-4
ethyl 2-diazo-3-oxobutanoate

: 95-57-8
2-monochlorophenol

: 32565-17-6
2-carbethoxy-3-methyl-7-chlorobenzofuran

Guidance literature:: Multi-step reaction with 2 steps

1: copper(II) bis(trifluoromethanesulfonate) / toluene / 2 h / 110 °C

2: polyphosphoric acid / 8 h / 85 °C

With copper(II) bis(trifluoromethanesulfonate); In toluene;
DOI:10.1134/S0012500818100051