azanide; dichlororuthenium

Base Information

Chemical Name:azanide; dichlororuthenium
CAS No.:63251-19-4
Molecular Formula:Cl*Cl₂H₁₂N₄Ru
Molecular Weight:275.551
Hs Code.:

Synonyms:

Suppliers and Price of azanide; dichlororuthenium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 14 raw suppliers

Chemical Property of azanide; dichlororuthenium

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of azanide; dichlororuthenium

There total 9 articles about azanide; dichlororuthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 16940-66-2
sodium tetrahydroborate

: 88288-72-6
Ru(O₂C₆H₃CO₂)(NH₃)4

: 22327-28-2,29230-00-0,63251-19-4
cis-tetramminedichlororuthenium(III) chloride

Guidance literature:: In hydrogenchloride; byproducts: 3,4-dihydroxybenzoic acid; Ru complex and acid mixing, NaBH4 carefull addn.; organic ligand extraction (ethylacetate), H2O2 addn. to aq. phase, heating, evapn. to dryness, residue recrystn. from aq. HCl;
DOI:10.1016/0020-1693(95)90086-L

Reference yield: 65.0%

: pentaamminechlororuthenium(III) dichloride

: calcium dithionate

: 144-62-7,97993-78-7
oxalic acid

: 22327-28-2,29230-00-0,63251-19-4
cis-tetramminedichlororuthenium(III) chloride

Guidance literature:: With ammonium hydroxide; Ar; a mixture of the starting complex and NH4OH was refluxed for 25 min; addn. of Ca(SO3)2; isoln. of (OH)(NH3)5Ru(SO3)2at 0° C; dissoln. in oxalic acid; reflux for 5 min; isolation of the oxalato-intermediate; reflux of a HCl-soln. for 10 min;; hot filtration; addn. of ethanol to the filtrate; cooling overnight at 0 ° C; filtration; recrystn. from warm 8 M HCl/ethanol; chilling at 0 ° C for 8 h;;