2-(Chloromethyl)-2-methyloxirane

Base Information

Chemical Name:2-(Chloromethyl)-2-methyloxirane
CAS No.:598-09-4
Molecular Formula:C4H7ClO
Molecular Weight:106.552
Hs Code.:2910900090
European Community (EC) Number:209-916-7
NSC Number:24245
DSSTox Substance ID:DTXSID50870659
Nikkaji Number:J4.366D
Mol file:598-09-4.mol

Synonyms:Propane,1-chloro-2,3-epoxy-2-methyl- (6CI,7CI,8CI);1,2-Epoxy-2-methyl-3-chloropropane;1,2-Epoxy-3-chloroisobutane;1-Chloro-2,3-epoxy-2-methylpropane;2-(Chloromethyl)-2-methyloxirane;2-Methyl-1-chloro-2,3-epoxypropane;2-Methyl-2-(chloromethyl)oxirane;2-Methylepichlorohydrin;3-Chloro-1,2-epoxy-2-methylpropane;Methepichlorohydrin;Methylepichlorohydrin;NSC 24245;b-Methylepichlorohydrin;

Suppliers and Price of 2-(Chloromethyl)-2-methyloxirane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-(Chloromethyl)-2-methyloxirane
50mg
$ 60.00

TCI Chemical
2-(Chloromethyl)-1,2-epoxypropane >98.0%(GC)
5g
$ 23.00

SynQuest Laboratories
3-Chloro-2-methyl-1,2-propenoxide
10 g
$ 148.00

SynQuest Laboratories
3-Chloro-2-methyl-1,2-propenoxide
1 g
$ 16.00

Matrix Scientific
2-(Chloromethyl)-2-methyloxirane 97%
1g
$ 10.00

Matrix Scientific
2-(Chloromethyl)-2-methyloxirane 97%
10g
$ 31.00

J&W Pharmlab
2-Chloromethyl-2-methyl-oxirane 96%
100g
$ 180.00

Biosynth Carbosynth
2-(Chloromethyl)-2-methyloxirane
100 g
$ 575.00

Biosynth Carbosynth
2-(Chloromethyl)-2-methyloxirane
50 g
$ 350.00

Biosynth Carbosynth
2-(Chloromethyl)-2-methyloxirane
25 g
$ 225.00

Total 61 raw suppliers

Chemical Property of 2-(Chloromethyl)-2-methyloxirane

Chemical Property:

Appearance/Colour:Colorless oil liquid
Vapor Pressure:17.1mmHg at 25°C
Melting Point:-40oC
Refractive Index:1.438
Boiling Point:121.999 °C at 760 mmHg
Flash Point:34.514 °C
PSA：12.53000
Density:1.12 g/cm³
LogP:1.01410
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:106.0185425
Heavy Atom Count:6
Complexity:64.6

Purity/Quality:

99% ^*data from raw suppliers

2-(Chloromethyl)-2-methyloxirane ^*data from reagent suppliers

Safty Information:

Pictogram(s): C
Hazard Codes:C
Statements: 20/21/22-34
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(CO1)CCl
General Description 2-(Chloromethyl)-2-methyloxirane, also known as 2-methyl epichlorohydrin or methylepichlorohydrin, is a chlorinated epoxide derived from the epoxidation of methallyl chloride (MAC). It can be efficiently synthesized using Ti-rich TS-1 as a catalyst with hydrogen peroxide (H₂O₂) in tert-butyl alcohol (TBA) solvent, achieving high conversion (85.4%) and selectivity (96.7%). The reaction proceeds via an Eley-Rideal-type mechanism involving active Ti-OOH intermediates formed on framework tetrahedral Ti species with moderate Br?nsted acidity. The catalytic performance is sensitive to reaction conditions, with alkali or salt additives drastically reducing activity. The epoxide's formation is favored under optimized parameters, including temperature, reactant ratios, and solvent concentration.

Technology Process of 2-(Chloromethyl)-2-methyloxirane

There total 10 articles about 2-(Chloromethyl)-2-methyloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%