Benzoic acid, 3,3'-methylenebis[5-bromo-2-hydroxy-

Base Information

• Chemical Name: Benzoic acid, 3,3'-methylenebis[5-bromo-2-hydroxy-
• CAS No.: 35232-55-4
• Molecular Formula: C15H10Br2O6
• Molecular Weight: 446.049
• NSC Number: 108640
• DSSTox Substance ID: DTXSID10296290
• Nikkaji Number: J360.952I
• Wikidata: Q82036811
• ChEMBL ID: CHEMBL323654
• Mol file: 35232-55-4.mol

Synonyms:35232-55-4;CHEMBL323654;benzoic acid, 3,3'-methylenebis[5-bromo-2-hydroxy-;NSC108640;DTXSID10296290;BDBM50219480;NSC-108640;5,5''-dibromo-3,3''-dicarboxy-2,2''-dihydroxydiphenylmethane;5-bromo-3-(5-bromo-3-carboxy-2-hydroxybenzyl)-2-hydroxybenzoic acid

Chemical Property of Benzoic acid, 3,3'-methylenebis[5-bromo-2-hydroxy-

Chemical Property:

• Boiling Point: 612.9°Cat760mmHg
• Flash Point: 324.5°C
• Density: 1.999g/cm³
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 445.88236
• Heavy Atom Count: 23
• Complexity: 419

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=C(C=C(C(=C1CC2=C(C(=CC(=C2)Br)C(=O)O)O)O)C(=O)O)Br

Technology Process of Benzoic acid, 3,3'-methylenebis[5-bromo-2-hydroxy-

There total 5 articles about Benzoic acid, 3,3'-methylenebis[5-bromo-2-hydroxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

5,5'-dibromo-3,3'-dicarbomethoxy-2,2'-dihydroxydiphenylmethane (954108-60-2) → 5,5'-dibromo-3,3'-dicarboxy-2,2'-dihydroxydiphenylmethane (35232-55-4)

Guidance literature:

With sodium hydroxide; In 1,4-dioxane; at 80 ℃; for 0.666667h;

DOI:10.1016/j.bmc.2007.07.010

Reference yield: 93.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 5-bromosalicyclic acid (89-55-4) → 5,5'-dibromo-3,3'-dicarboxy-2,2'-dihydroxydiphenylmethane (35232-55-4)

Guidance literature:

In methanol; 1.) 0 deg C, 2 h, 2.) RT, 14 h;

DOI:10.1021/jm00105a053

Reference yield: 51.0%

1-[3-(3-Acetyl-5-bromo-2-hydroxy-benzyl)-5-bromo-2-hydroxy-phenyl]-ethanone (83143-04-8) → 5,5'-dibromo-3,3'-dicarboxy-2,2'-dihydroxydiphenylmethane (35232-55-4)

Guidance literature:

With sodium hypoiodite;

DOI:10.1002/hlca.19820650411

upstream raw materials:

formaldehyd

5-bromosalicyclic acid

1-[3-(3-Acetyl-5-bromo-2-hydroxy-benzyl)-5-bromo-2-hydroxy-phenyl]-ethanone

5,5'-dibromo-3,3'-dicarbomethoxy-2,2'-dihydroxydiphenylmethane

Downstream raw materials:

5,5'-dibromo-3,3'-dicarbomethoxy-2,2'-dimethoxydiphenylmethane

5,5'dibromo-2,2'-dimethoxy-3,3'dicarbomethoxybenzophenone

3,3'-dicarbomethoxy-2,2'-dihydroxydiphenylmethane

3,3'-dicarboxy-2,2'-dihydroxydiphenylmethane