Bismuth; nickel

Base Information

• Chemical Name: Bismuth; nickel
• CAS No.: 12688-64-1
• Molecular Formula: BiNi
• Molecular Weight: 267.67
• European Community (EC) Number: 235-773-5
• DSSTox Substance ID: DTXSID4065315
• Mol file: 12688-64-1.mol

Synonyms:bismuth;nickel;12688-64-1;Bi.Ni;EINECS 235-773-5;DTXSID4065315;Bismuth, compound with nickel (1:1)

Chemical Property of Bismuth; nickel

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.33750
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 266.91574
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

NICKEL BISMUTHIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Ni].[Bi]

Technology Process of Bismuth; nickel

There total 4 articles about Bismuth; nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bismuth (III) nitrate pentahydrate + ammonium nickel(II) sulfate hexahydrate → bismuth (7440-69-9) + nickel bismuthide (12688-64-1) + nickel (bismuthide)3 + nickel (7440-02-0)

Guidance literature:

With N₂H₄*H₂O; In water; High Pressure; Bi(NO3)3*5H2O and Ni(NH4)2(SO4)2*6H2O (in stoich. ratio) dissolved in water under rapid sterring for 15 min; N2H4*H2O slowly added, maintained in autoclave at 150°C for 18 h; washed (H2O and EtOH);

DOI:10.1016/j.jallcom.2005.03.063

Reference yield:

bismuth (7440-69-9) + nickel (7440-02-0) → nickel bismuthide (12688-64-1)

Guidance literature:

In neat (no solvent); Ni and Bi mixtured was powdered for several times, heated and then tempered at 500 °C for 24 h;;

Reference yield:

bismuth (III) nitrate pentahydrate + nickel(II) acetate tetrahydrate (6018-89-9) → nickel bismuthide (12688-64-1)

Guidance literature:

In ethylene glycol; at 240 ℃; for 0.5h; Microwave irradiation;

DOI:10.1002/ejic.201700966

upstream raw materials:

bismuth

nickel

nickel(II) acetate tetrahydrate