Bismuth

Base Information

• Chemical Name: Bismuth
• CAS No.: 7440-69-9
• Deprecated CAS: 24267-48-9,25243-76-9
• Molecular Formula: Bi
• Molecular Weight: 208.98
• Hs Code.: 81060010
• European Community (EC) Number: 231-177-4
• DSSTox Substance ID: DTXSID3052484
• Wikipedia: Bismuth
• Wikidata: Q942,Q4918361
• NCI Thesaurus Code: C95193
• Mol file: 7440-69-9.mol

Synonyms:Bismuth

Chemical Property of Bismuth

Chemical Property:

• Appearance/Colour: silver-grey or reddish metal, or black powder
• Vapor Pressure: <0.1 mm Hg ( 20 °C)
• Melting Point: 271 °C(lit.)
• Boiling Point: 1560 °C
• PSA: 0.00000
• Density: 9.8 g/cm³
• LogP: 0.33750
• Storage Temp.: Flammables area
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 208.98040
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

99.99% ^*data from raw suppliers

Bismuth powder, 100 mesh, ≥99.99% trace metals basis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C
• Hazard Codes: F,C,Xi,O
• Statements: 34-11-36/37/38-8
• Safety Statements: 16-45-36/37/39-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Elements, Metallic
• Canonical SMILES: [Bi]
• Recent ClinicalTrials: A Study to Test How Healthy Women Tolerate Different Doses of BI 1819479
• Recent EU Clinical Trials: Kan mineraltilskud med bismuth mindske toksiciteten af kemoterapi og str?lebehandling? En klinisk prospektiv, dobbeltblind randomiseret unders?gelse af patienter med h?matologiske sygdomme som modtager intensiv kemoterapi og /eller str?lebehandling.
• Recent NIPH Clinical Trials: Berberine containing therapy for Helicobacter Pylori treatment among patients with previous failed eradication
• Description: Bismuth is a white, crystalline, brittle metal with a pinkish tinge. Bismuth is the most diamagnetic of all metals, and the thermal conductivity is lower than any metal. It occurs naturally in the metallic state and in minerals such as bismite. The most important ores are bismuthinite or bismuth glance and bismite, and countries such as Peru, Japan, Mexico, Bolivia, and Canada are major producers of bismuth. It is found as crystals in the sulphide ores of nickel, cobalt, silver, and tin. Bismuth is mainly produced as a by-product from lead and copper smelting. It is insoluble in hot or cold water. Bismuth explodes if mixed with chloric or perchloric acid. Molten bismuth explodes and bismuth powder glows red-hot on contact with concentrated nitric acid. It is flammable in powder form. Bismuth is used in the manufacture of low melting solders and fusible alloys; as key components of thermoelectric safety appliances, such as automatic shut-offs for gas and electric water-heating systems and safety plugs in compressed gas cylinders; in the production of shot and shotguns; in pharmaceuticals; in the manufacturing of acrylonitrile; and as the starting material for synthetic fibres and rubbers. Bismuth oxychloride is sometimes used in cosmetics. Also bismuth subnitrate and bismuth subcarbonate are used in medicine. Bismuth subsalicylate is used as an anti-diarrhoeal and as a treatment of some other gastrointestinal diseases.
• Physical properties: Bismuth has unusually low toxicity for a heavy metal. Bismuth is stable to both dry and moist air at ordinary temperatures. When red hot, it reacts with water to make bismuth(III) oxide. Bismuth forms trivalent and pentavalent compounds. The trivalent compounds are more common. Many of its chemical properties are similar to those of As and Sb, although they are less toxic than derivatives of those lighter elements. At elevated temperatures, the vapors of the metal combine rapidly with oxygen, forming the yellow trioxide, Bi2O3.
• Uses: Bismuth is used to make the drugs such as Pepto-Bismol for upset stomachs and diarrheaand in medicine to treat intestinal infections. Bismuth is used in the cosmetics industry toprovide the “shine” for lipsticks, eye shadow, and other products.It is added to steel and other metals as an alloy to make the metals easier to roll, press, pullinto wires, and turn on a lathe. It is also used in the semiconductor industry and to makepermanent magnets.Bismuth is similar to antimony in that it expands from the molten liquid state to the solidstate. This property makes it an excellent material to pour into molds and can produce finedetails in whatever is being molded, such as metallic printing type and similar fine castings. Several bismuth compounds have been used medicinally. Some are used for gastrointestinal distress (Pepto-Bismol contains bismuth subsalicylate). Others are used as salves and, in rare cases, for treatment of parasites. In the past, bismuth was also used to treat syphilis and malaria. Commercially, bismuth is also used in the manufacture of permanent magnets, semiconductors, and thermoelectric materials; as a catalyst in making acrylonitrile; and as an additive to improve the machinability of steels and other metals. Bismuth is also frequently used in cosmetics, generally nail polish and lipstick.

Technology Process of Bismuth

There total 365 articles about Bismuth which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

tris(pentafluorophenyl)bismuth (34422-57-6) → bismuth (7440-69-9) + bismuth hydroxide + Pentafluorobenzene (363-72-4) + decafluorobiphenyl (434-90-2)

Guidance literature:

With water;

DOI:10.1016/0020-1650(72)80068-0

Reference yield:

bismuth(III) sulfide → bismuth (7440-69-9) + hydrogen sulfide (7783-06-4)

Guidance literature:

With hydrogen; reaction of Bi2S3 in a strem of H2 (2 l/hour), stimulating voltage 15 kV;;

Reference yield:

bismuth(III) sulfate → bismuth (7440-69-9) + bismuth(III) sulfide + hydrogen sulfide (7783-06-4)

Guidance literature:

With hydrogen; In neat (no solvent); byproducts: H2O; reduction of Bi sulfate in a discharge tube at 15 kV under H2 (2 l/hour) at 25°C;;

upstream raw materials:

bismuth(III) oxide

formic acid

triphenylbismuthane

tin tetrachloride hydrate

Downstream raw materials:

bismuth(III) iodide

boron triiodide

bismuth(II) oxide

bismuth(III) bromide

Refernces

• 1、 Chen, Sinn-Wen,Wu, Chih-Yu,Wu, Hsin-Jay,Chiu, Wan-Ting. "Interfacial reactions in Sn/Bi2Te3, Sn/Bi 2Se3 and Sn/Bi2(Te1-xSe x)3 couples". . p. 313 - 318. Retrieved 2014.
• 2、 Chen, Dongling,Zhang, Min,Lu, Qiuju,Chen, Junfang,Liu, Bitao,Wang, Zhaofeng. "Facile synthesis of Bi/BiOCl composite with selective photocatalytic properties". . p. 647 - 654. Retrieved 2015.
• 3、 Gao, Zheng,Qin, Haiming,Yan, Tao,Liu, Hong,Wang, Jiyang. "Structure and resistivity of bismuth nanobelts in situ synthesized on silicon wafer through an ethanol-thermal method". . p. 3257 - 3261. Retrieved 2011.
• 4、 Liu, Kai,Chien,Searson,Yu-Zhang, Kui. "Structural and magneto-transport properties of electrodeposited bismuth nanowires". . p. 1436 - 1438. Retrieved 1998.
• 5、 Li, Wei,Xu, Yang,Dong, Yulian,Wu, Yuhan,Zhang, Chenglin,Zhou, Min,Fu, Qun,Wu, Minghong,Lei, Yong. "Bismuth oxychloride nanoflake assemblies as a new anode for potassium ion batteries". . p. 6507 - 6510. Retrieved 2019.
• 6、 Huang, Chaur-Chi,Wen, Teng-Yi,Fung, Kuan-Zong. "Orientation-controlled phase transformation of Bi2O3 during oxidation of electrodeposited Bi film". . p. 110 - 118. Retrieved 2006.
• 7、 Ragoisha,Bondarenko. "Potentiodynamic electrochemical impedance spectroscopy". . p. 1553 - 1563. Retrieved 2005.
• 8、 Stewart, Constantine A.,Calabrese, Joseph C.,Arduengo, Anthony J. III. "". . p. 3397 - 3398. Retrieved 1985.
• 9、 Sand, H. J. S.. "". . p. 373 - 410. Retrieved 1907.
• 10、 Wehrman, R.,Yntema, L. F.. "". . p. 259 - 268. Retrieved 1944.