1-METHOXYDECANE

Base Information

• Chemical Name: 1-METHOXYDECANE
• CAS No.: 7289-52-3
• Molecular Formula: C11H24 O
• Molecular Weight: 172.311
• European Community (EC) Number: 230-718-1,273-565-6
• DSSTox Substance ID: DTXSID6064616
• Nikkaji Number: J75.049B
• Wikidata: Q3333693
• Mol file: 7289-52-3.mol

Synonyms:Ether,decyl methyl (7CI,8CI); 1-Methoxydecane; Decyl methyl ether; Methyl decylether; Methyl n-decyl ether

Chemical Property of 1-METHOXYDECANE

Chemical Property:

• Appearance/Colour: colorless clear liquid
• Melting Point: 189 °C
• Refractive Index: 1.4102 (estimate)
• Boiling Point: 215.2 °C at 760 mmHg
• Flash Point: 72.9 °C
• PSA: 9.23000
• Density: 0.795 g/cm³
• LogP: 3.77350
• Storage Temp.: Refrigerator
• Solubility.: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 172.182715385
• Heavy Atom Count: 12
• Complexity: 71.4

Purity/Quality:

99%, ^*data from raw suppliers

DecylMethylEther ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCOC
• Uses: Fragrance/Aroma compound with a fresh scent. Decyl Methyl Ether is a fatty ether used as a possible diesel fuel extender. 1-METHOXYDECANE is a fatty ether used as a possible diesel fuel extenders.

Technology Process of 1-METHOXYDECANE

There total 20 articles about 1-METHOXYDECANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

n-octylmagnesium chloride (38841-98-4) + 2-Bromoethyl methyl ether (6482-24-2) → 1-methoxydecane (7289-52-3)

Guidance literature:

With [((Me)NN₂)NiCl]; In tetrahydrofuran; ISOPROPYLAMIDE; at -35 - 20 ℃; Inert atmosphere;

Reference yield: 95.3%

1,1-dimethoxy decane (7779-41-1) → 1-methoxydecane (7289-52-3)

Guidance literature:

With triethylsilane; Naftion-H (perfluororesinsulfonic acid); In dichloromethane; for 2h; Heating;

DOI:10.1021/jo00364a044

Reference yield: 95.0%

1-Decanol (112-30-1) + methyl iodide (74-88-4) → 1-methoxydecane (7289-52-3)

Guidance literature:

With potassium hydroxide; at 20 ℃; for 14h;

upstream raw materials:

1-Decanol

1-methyl pyridinium iodide

methanol

1-bromo dodecane

Downstream raw materials:

Methyl decanoate

n-decyl methanoate

decane

Refernces

• 1、 Parrott, Andrew J.,Bourne, Richard A.,Gooden, Peter N.,Poliakoff, Martyn,Irvine, Derek J.,Bevinakatti, Han. S.. "The continuous acid-catalysed etherification of aliphatic alcohols using stoichiometric quantities of dialkyl carbonates". experimental part. p. 1420 - 1426. Retrieved 2011/09/20.
• 2、 Vechorkin, Oleg,Hu, Xile. "Nickel-catalyzed cross-coupling of non-activated and functionalized alkyl halides with alkyl grignard reagents". supporting information; experimental part. p. 2937 - 2940. Retrieved 2009/09/08.