cyclohexanamine, platinum(+2) cation, dichloride

Base Information

• Chemical Name: cyclohexanamine, platinum(+2) cation, dichloride
• CAS No.: 56846-70-9
• Molecular Formula: C₁₂H₂₆Cl₂N₂Pt
• Molecular Weight: 464.338
• Mol file: 56846-70-9.mol

Synonyms:Cyclohexanamine,platinum complex; trans-Dichlorobis(cyclohexylamine)platinum;trans-Dichlorobis(cyclohexylamine)platinum(II)

Chemical Property of cyclohexanamine, platinum(+2) cation, dichloride

Chemical Property:

• Vapor Pressure: 8.07mmHg at 25°C
• Boiling Point: 134.5°Cat760mmHg
• Flash Point: 32.2°C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cyclohexanamine, platinum(+2) cation, dichloride

There total 6 articles about cyclohexanamine, platinum(+2) cation, dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

C24H52N4Pt(2+)*2Cl(1-) → trans-bis(cyclohexylamine)dichloroplatinum(II) (38780-35-7,56846-70-9,176705-98-9)

Guidance literature:

In N,N-dimethyl-formamide; at 120 ℃; for 3h;

DOI:10.1016/j.poly.2012.08.010

Reference yield: 21.0%

potassium tetrachloroplatinate(II) (10025-99-7) + cyclohexylamine (108-91-8,157973-60-9) → cis-dichlorobis(cyclohexylamine)platinum(II) (38780-35-7,56846-70-9,176705-98-9)

Guidance literature:

In water; addn. of cyclohexylamine to an aq. soln. of K2PtCl4 and stirring at room temp. for 2 h; filtering off the yellow complex, washing with water, methanol an diethyl ether and drying under vacuum, elem. anal.;

DOI:10.1007/BF00819526

Reference yield:

cis-[diiodobis(cyclohexylamino)platinum(II)] (102806-98-4,127305-59-3) + potassium chloride → cis-dichlorobis(cyclohexylamine)platinum(II) (38780-35-7,56846-70-9,176705-98-9)

Guidance literature:

In not given; an adapted version of Dhara's method (Indian J. Chem. 8 (1970) 193); diaqua species obtained from Pt complex, reacted with KCl; ppt. washed (H2O), dried;

DOI:10.1016/j.ica.2004.12.030

upstream raw materials:

cis-[diiodobis(cyclohexylamino)platinum(II)]

potassium tetrachloroplatinate(II)

cyclohexylamine

trans-[diiodobis(cyclohexylamino)platinum(II)]

Downstream raw materials:

cis-bis(cyclohexylamine)tetrachloroplatinum(IV)

trans-bis(cyclohexylamine)dichloroplatinum(II)

C₁₂H₂₈Cl₂N₂O₂Pt

trans-bis(cyclohexylamine)tetrachloroplatinum(IV)

Refernces

• 1、 Johnstone, Timothy C.,Lippard, Stephen J.. "Conformational isomerism of trans-[Pt(NH2C6H 11)2I2] and the classical Wernerian chemistry of [Pt(NH2C6H11)4]X2 (X = Cl, Br, I)". . p. 565 - 575. Retrieved 2013/06/27.
• 2、 Kritzenberger, J.,Bernhardt, G.,Gust, R.,Pistor, P.,Schoenenberger, H.,Yersin, H.. "Dichlorobis(cycloalkylamine)platinum(II) Complexes. Structure Activity Relationship on the Human MDA-MB-231 Breast Cancer Cell Line". . p. 587 - 605. Retrieved 2007/10/02.