3,6-dimethylcyclohexene

Base Information

• Chemical Name: 3,6-dimethylcyclohexene
• CAS No.: 19550-40-4
• Molecular Formula: C8H14
• Molecular Weight: 110.199
• Mol file: 19550-40-4.mol

Synonyms:Cyclohexene, 3,6-dimethyl-;Cyclohexene,3,6-dimethyl;

Chemical Property of 3,6-dimethylcyclohexene

Chemical Property:

• Vapor Pressure: 16.7mmHg at 25°C
• Boiling Point: 122.5°C at 760 mmHg
• Flash Point: 6.8°C
• PSA: 0.00000
• Density: 0.788g/cm³
• LogP: 2.60860

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,6-dimethylcyclohexene

There total 12 articles about 3,6-dimethylcyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.5%

4-methyl-cyclohex-3-enecarbaldehyde (7560-64-7) → 3-methyl-1-cyclohexene (591-48-0) + para-xylene (106-42-3) + 3,6-dimethylcyclohex-1-ene (19550-40-4) + methyl cyclohexane (82166-21-0) + toluene (108-88-3,15644-74-3,16713-13-6)

Guidance literature:

With hydrogen; In hexane; at 275 ℃; Flow reactor; Green chemistry;

DOI:10.1039/d0gc00944j

Reference yield:

isoprene (78-79-5,9003-31-0) → 3-methyl-1-cyclohexene (591-48-0) + para-xylene (106-42-3) + 3,6-dimethylcyclohex-1-ene (19550-40-4) + methyl cyclohexane (82166-21-0) + toluene (108-88-3,15644-74-3,16713-13-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 1-methyl-3-butylimidazolium zinc chloride / 24 h / 25 °C

2: hydrogen / hexane / 275 °C / Flow reactor; Green chemistry

With 1-methyl-3-butylimidazolium zinc chloride; hydrogen; In hexane; 1: |Diels-Alder Cycloaddition;

DOI:10.1039/d0gc00944j

Reference yield:

(2E,4E)-hexa-2,4-diene (5194-51-4) + ethene (74-85-1) → 3,6-dimethylcyclohex-1-ene (19550-40-4)

Guidance literature:

(^iPr₄Anthraphos)Ir(C₂H₄); at 250 ℃; for 48h; under 25858.1 Torr; Sealed vessel;

upstream raw materials:

ethene

hexa-2,4-diene

methylmagnesium bromide

(2E,4E)-hexa-2,4-diene

Downstream raw materials:

para-xylene

1-chloro-2-pentafluorosulfanylcyclohexane