2-Phenylpicolinium iodide

Base Information

• Chemical Name: 2-Phenylpicolinium iodide
• CAS No.: 52806-02-7
• Molecular Formula: C12H12IN
• Molecular Weight: 297.138
• DSSTox Substance ID: DTXSID80967268
• Mol file: 52806-02-7.mol

Synonyms:2-Phenylpicolinium iodide;Pan-W-49;PICOLINIUM, 2-PHENYL-, IODIDE;1-methyl-2-phenylpyridin-1-ium iodide;Pyridinium, 1-methyl-2-phenyl-, iodide;52806-02-7;DTXSID80967268;LS-109732

Chemical Property of 2-Phenylpicolinium iodide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 297.00145
• Heavy Atom Count: 14
• Complexity: 149

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[N+]1=CC=CC=C1C2=CC=CC=C2.[I-]

Technology Process of 2-Phenylpicolinium iodide

There total 5 articles about 2-Phenylpicolinium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2-phenylpyridine (1008-89-5) + methyl iodide (74-88-4) → iodure de 1-methyl-2-phenylpyridinium (52806-02-7)

Guidance literature:

In acetonitrile; at 90 ℃; for 16h; Inert atmosphere;

DOI:10.1002/adsc.201800666

Reference yield: 54.0%

tributylphenylstannane (960-16-7) + 2-bromo-1-methyl-pyridinium iodide (52693-56-8) → iodure de 1-methyl-2-phenylpyridinium (52806-02-7)

Guidance literature:

With tris-(o-tolyl)phosphine; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1055/s-2002-34903

Reference yield:

1-methyl-2-phenylpyridin-1-ium-6-d iodide → iodure de 1-methyl-2-phenylpyridinium (52806-02-7)

Guidance literature:

With potassium pivalate; In N,N-dimethyl acetamide; at 100 ℃; for 0.5h; Schlenk technique; Sealed tube; Inert atmosphere;

DOI:10.1002/adsc.201800666

upstream raw materials:

2-phenylpyridine

methyl iodide

tributylphenylstannane

2-bromo-1-methyl-pyridinium iodide

Downstream raw materials:

2-(4-methoxyphenyl)-6-phenylpyridine

2-(4-fluorophenyl)-6-phenylpyridine

2-(4-nitrophenyl)-6-phenylpyridine

2-phenyl-6-(o-tolyl)pyridine