Triisobutylchlorosilane

Base Information

• Chemical Name: Triisobutylchlorosilane
• CAS No.: 13154-25-1
• Molecular Formula: C12H27ClSi
• Molecular Weight: 234.88
• Hs Code.: 2931900090
• European Community (EC) Number: 454-150-0,627-295-4
• NSC Number: 516680
• DSSTox Substance ID: DTXSID70325737
• Nikkaji Number: J1.536.039I
• Wikidata: Q72513606
• Mol file: 13154-25-1.mol

Synonyms:Triisobutylchlorosilane;13154-25-1;Chlorotriisobutylsilane;chloro-tris(2-methylpropyl)silane;Silane, chlorotris(2-methylpropyl)-;NSC 516680;Silane,chlorotris(2-methylpropyl)-;NSC516680;triisobutyl-chlorosilane;TRI-N-OCTYLTINHYDRIDE;Chlorotriisobutylsilane, 99%;SCHEMBL549136;chlorotris(2-methylpropyl)silane;DTXSID70325737;MFCD00010658;NSC-516680;[Si](Cl)(CC(C)C)(CC(C)C)CC(C)C;FT-0636817;Triisobutylchlorosilane, Triisobutylsilyl chloride;J-006019

Chemical Property of Triisobutylchlorosilane

Chemical Property:

• Vapor Pressure: 0.0301mmHg at 25°C
• Refractive Index: n20/D 1.448(lit.)
• Boiling Point: 252.87 °C at 760 mmHg
• Flash Point: 87.778 °C
• PSA: 0.00000
• Density: 0.855 g/cm³
• LogP: 5.13870
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 234.1570551
• Heavy Atom Count: 14
• Complexity: 126

Purity/Quality:

97% ^*data from raw suppliers

Chlorotriisobutylsilane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)C[Si](CC(C)C)(CC(C)C)Cl
• Uses: Chlorotriisobutylsilane can be used as an intermediate in the synthesis of:Silicon (IV) phthalocyanines, which are used as photosensitizers for the photodynamic?inactivation?of?bacteria.Poly(4-alkylthiazole) polymers exhibiting optical and electronic properties.Bis(trialkylsilyl oxide) based silicon phthalocyanines applicable as ternary additives in organic photovoltaics.

Technology Process of Triisobutylchlorosilane

There total 1 articles about Triisobutylchlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ triiso-butylchlorosilane (13154-25-1)

Guidance literature:

Tetrachlor-silan, Isobutyl-lithium;

DOI:10.1016/S0022-328X(00)81512-0

Reference yield: 91.0%

triiso-butylchlorosilane (13154-25-1) + (+)-(3S,SS)-(4E)-4-(p-tolylsulfinyl)hepta-4,6-dien-3-ol → (+)-(3S,4E,SS)-triisobutyl [4-(p-tolylsulfinyl)hepta-4,6-dien-3-yloxy]silane

Guidance literature:

With dmap; triethylamine; In N,N-dimethyl-formamide; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/chem.201905742

Reference yield: 63.0%

(+)-(5S,S(S))-(4E)-4-(p-tolylsulfinyl)deca-1,3-dien-5-ol (951133-45-2) + triiso-butylchlorosilane (13154-25-1) → (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triisobutylsilane (951133-52-1)

Guidance literature:

With dmap; triethylamine; In N,N-dimethyl-formamide; at 0 - 20 ℃;

DOI:10.1016/j.tetlet.2007.07.058

Downstream raw materials:

Tetrahydro-2-<<3-(triisobutylsilyl)-2-propynyl>oxy>-2H-pyran

(+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triisobutylsilane

3-(Triisobutylsilyl)propargyl ethyl carbonate

2(S)-(2-methylphenyl)-1-<((1R,2S,5R)-8-phenylmenthoxy)carbonyl>-5-(triisobutylsilyl)-2,3-dihydro-4-pyridone