5,6-dimethyl-2-phenyl-1H-benzo[d]imidazole

Base Information

• Chemical Name: 5,6-dimethyl-2-phenyl-1H-benzo[d]imidazole
• CAS No.: 14313-45-2
• Molecular Formula: C15H14 N2
• Molecular Weight: 222.29
• NSC Number: 128745
• DSSTox Substance ID: DTXSID10299201
• Nikkaji Number: J2.327.761A
• Wikidata: Q82041446
• Mol file: 14313-45-2.mol

Synonyms:5,6-dimethyl-2-phenyl-1H-benzo[d]imidazole;14313-45-2;5,6-dimethyl-2-phenyl-1h-benzimidazole;NSC128745;SCHEMBL3337332;DTXSID10299201;MFCD03783532;NSC-128745;FT-0730186;F15168

Chemical Property of 5,6-dimethyl-2-phenyl-1H-benzo[d]imidazole

Chemical Property:

• Vapor Pressure: 1.78E-07mmHg at 25°C
• Boiling Point: 426.4°Cat760mmHg
• Flash Point: 224.6°C
• Density: 1.152g/cm³
• XLogP3: 4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 222.115698455
• Heavy Atom Count: 17
• Complexity: 260

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC2=C(C=C1C)N=C(N2)C3=CC=CC=C3

Technology Process of 5,6-dimethyl-2-phenyl-1H-benzo[d]imidazole

There total 34 articles about 5,6-dimethyl-2-phenyl-1H-benzo[d]imidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

benzaldehyde (100-52-7) + 4,5-dimethyl-1,2-phenylenediamine (3171-45-7) → 5,6-dimethyl-2-phenyl-1H-benzo[d]imidazole (14313-45-2)

Guidance literature:

With air; TZ-HCP₁D polymer; In ethanol; at 20 ℃; for 1h; Irradiation;

DOI:10.1039/d0gc03719b

Reference yield: 98.0%

4,5-dimethyl-2-nitrobenzenamine (6972-71-0) + benzaldehyde (100-52-7) → 5,6-dimethyl-2-phenyl-1H-benzo[d]imidazole (14313-45-2)

Guidance literature:

With hydrogen; In ethyl acetate; at 60 ℃; for 20h; under 7500.75 Torr; Autoclave; Green chemistry;

DOI:10.1002/cssc.202002344

Reference yield: 97.0%

N-(2-amino-4,5-dimethylphenyl)benzamide oxime (86255-32-5) → 5,6-dimethyl-2-phenyl-1H-benzo[d]imidazole (14313-45-2)

Guidance literature:

With hydrogenchloride; In methanol; for 0.166667h; Heating;

upstream raw materials:

N-(3,4-dimethyl-phenyl)-benzamide oxime

benzaldehyde

4,5-dimethyl-1,2-phenylenediamine

benzonitrile

Downstream raw materials:

5,6-dimethyl-1-methylsulphanylmethyl-2-phenyl-1H-benzimidazole

9,10-dimethyl-6-phenylbenzo[4,5]imidazo[2,1-a]isoquinoline

9,10-dimethyl-6-(p-tolyl)benzo[4,5]imidazo[2,1-a]isoquinoline