Methyl 2-O-mesyl-3,4-isopropylidene-beta-d-arabinoside

Base Information

Chemical Name:Methyl 2-O-mesyl-3,4-isopropylidene-beta-d-arabinoside
CAS No.:3945-23-1
Molecular Formula:C₁₀H₁₈O₇S
Molecular Weight:282.315
Hs Code.:
NSC Number:170216,108084
DSSTox Substance ID:DTXSID50960089

Synonyms:3945-23-1;NSC170216;DTXSID50960089;ZKVBPEGCESZAPG-UHFFFAOYSA-N;NSC108084;NSC-108084;NSC-170216;Methyl 2-O-mesyl-3,4-isopropylidene-.beta.-d-arabinoside;Methyl 2-O-(methanesulfonyl)-3,4-O-(1-methylethylidene)pentopyranoside;Methyl 3,4-O-(1-methylethylidene)-2-O-(methylsulfonyl)pentopyranoside #

Suppliers and Price of Methyl 2-O-mesyl-3,4-isopropylidene-beta-d-arabinoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Methyl 2-O-mesyl-3,4-isopropylidene-beta-d-arabinoside

Chemical Property:

Vapor Pressure:1.06E-06mmHg at 25°C
Refractive Index:1.498
Boiling Point:414.5°Cat760mmHg
Flash Point:204.5°C
Density:1.34g/cm³
XLogP3:-0.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:3
Exact Mass:282.07732408
Heavy Atom Count:18
Complexity:399

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(OC2COC(C(C2O1)OS(=O)(=O)C)OC)C

Technology Process of Methyl 2-O-mesyl-3,4-isopropylidene-beta-d-arabinoside

There total 9 articles about Methyl 2-O-mesyl-3,4-isopropylidene-beta-d-arabinoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 67-56-1
methanol

: 110237-75-7
3,4-O-isopropylidene-2-O-methanesulfonyl-β-D-arabinopyranosyl chloride

: 863998-30-5,3945-23-1
methyl 3,4-O-isopropylidene-2-O-methanesulfonyl-β-D-arabinopyranoside

: 863998-29-2,3945-23-1
methyl 3,4-O-isopropylidene-2-O-methanesulfonyl-α-D-arabinopyranoside

Guidance literature:: With silver(l) oxide; at 20 ℃; for 20h;
DOI:10.1016/j.carres.2005.06.006

Reference yield: 51.0%

: 67-56-1
methanol

: 110237-75-7
3,4-O-isopropylidene-2-O-methanesulfonyl-β-D-arabinopyranosyl chloride

: 863998-30-5,3945-23-1
methyl 3,4-O-isopropylidene-2-O-methanesulfonyl-β-D-arabinopyranoside

: 863998-29-2,3945-23-1
methyl 3,4-O-isopropylidene-2-O-methanesulfonyl-α-D-arabinopyranoside

Guidance literature:: With silver(l) oxide; at 20 ℃; for 20h;
DOI:10.1016/j.carres.2005.06.006

Reference yield:

: 91-09-8,612-05-5,1825-00-9,2500-78-9,3867-83-2,3945-28-6,5328-63-2,6206-67-3,6207-01-8,6207-03-0,7404-24-2,14703-09-4,17289-61-1,18449-76-8,33509-64-7,36793-06-3,41897-31-8,41897-32-9,41897-33-0,41897-34-1,41897-37-4,41897-38-5,41897-39-6,53448-52-5,65137-86-2,89615-04-3,89615-05-4,131233-91-5
(2S,3S,4R,5R)-2-Methoxy-tetrahydro-pyran-3,4,5-triol

: 863998-29-2,3945-23-1
methyl 3,4-O-isopropylidene-2-O-methanesulfonyl-α-D-arabinopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: concentrated sulfuric acid; copper (II)-sulfate

2: pyridine

With pyridine; sulfuric acid; copper(II) sulfate;
DOI:10.1039/jr9490001235 DOI:10.1021/ja01552a056