1-chloro-4-(2-phenylethyl)benzene

Base Information

• Chemical Name: 1-chloro-4-(2-phenylethyl)benzene
• CAS No.: 14310-22-6
• Molecular Formula: C14H13 Cl
• Molecular Weight: 216.71
• Mol file: 14310-22-6.mol

Synonyms:Bibenzyl,4-chloro- (6CI,7CI,8CI); 1-(4-Chlorophenyl)-2-phenylethane; 4-Chlorobibenzyl;NSC 11134

Chemical Property of 1-chloro-4-(2-phenylethyl)benzene

Chemical Property:

• Vapor Pressure: 0.00372mmHg at 25°C
• Boiling Point: 289.9°C at 760 mmHg
• Flash Point: 117.4°C
• Density: 1.111g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-chloro-4-(2-phenylethyl)benzene

There total 39 articles about 1-chloro-4-(2-phenylethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-chloro-4-styrylbenzene (1657-49-4,1657-50-7,4714-23-2,130059-92-6,130059-96-0) → 4-chlorobibenzyl (14310-22-6)

Guidance literature:

With hydrogen; In methanol; at 20 ℃; for 5h; chemoselective reaction;

DOI:10.1002/aoc.4767

Reference yield: 98.0%

4-vinylbenzyl chloride (1073-67-2,24991-47-7) + bromobenzene (108-86-1,52753-63-6) → 4-chlorobibenzyl (14310-22-6)

Guidance literature:

4-vinylbenzyl chloride; bromobenzene; With sodium acetate; In N,N-dimethyl acetamide; at 100 ℃; Inert atmosphere;

With hydrogen; In N,N-dimethyl acetamide; at 20 ℃; under 760.051 Torr;

DOI:10.1002/adsc.200800460

Reference yield: 98.0%

1-(2-bromoethyl)-4-chlorobenzene (6529-53-9) + phenylmagnesium chloride (100-59-4) → 4-chlorobibenzyl (14310-22-6)

Guidance literature:

With N,N,N,N,-tetramethylethylenediamine; [((Me)NN₂)NiCl]; In tetrahydrofuran; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ja9027378

upstream raw materials:

N-benzyl-N-(4-chloro-benzyl)-hydrazine

Triphenyl-<1-phenyl-2-(4-chlorphenyl)-aethyl>-phosphoniumchlorid

1-chloro-4-(2-chloroethyl)benzene

benzene

Downstream raw materials:

4,5-Diphenyl-2,3-bis-(p-chlor-phenyl)-(αβ)-cyclopentadien-(2,4)-on-(1)

4-Phenyl-2,3,5-tris-(p-chlor-phenyl)-(αα'β)-cyclopentadien-(2,4)-on-(1)

bibenzyl-4-yl-acetonitrile