CID 6330383

Base Information

• Chemical Name: CID 6330383
• CAS No.: 13937-05-8
• Molecular Formula: C16H40 Ge3
• Molecular Weight: 450.264
• NSC Number: 179716
• Mol file: 13937-05-8.mol

Synonyms:NSC179716;NSC-179716

Chemical Property of CID 6330383

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 8
• Exact Mass: 448.080503
• Heavy Atom Count: 19
• Complexity: 96.1

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Ge]CC.CC[Ge](CC)CC.CC[Ge](CC)CC

Technology Process of CID 6330383

There total 4 articles about CID 6330383 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(HO((CH3)3C)2C6H2)2CHGeCl3 (153789-55-0) + Coppinger's Radikal (22719-43-3,2370-18-5) + ethylmagnesium bromide (925-90-6) → (HO((CH3)3C)2C6H2)2CHGeH3 (153789-57-2) + hexaethyldigermane (993-62-4) + octaethyltrigermane (13937-05-8)

Guidance literature:

With lithium aluminium tetrahydride; water; In tetrahydrofuran; Ge-compd. soln. (THF) redn. with LiAlH4 soln. (ether) (0°C), hydrolyse; reaction soln. drying over Na2SO4, concn. (reduced pressure);

Reference yield: 80.0%

Coppinger's Radikal (22719-43-3,2370-18-5) + ethylmagnesium bromide (925-90-6) + germanium hydride trichloride (1184-65-2) → tetraethylgermane (597-63-7) + hexaethyldigermane (993-62-4) + octaethyltrigermane (13937-05-8)

Guidance literature:

With water; In tetrahydrofuran; treatment od reaction mixt. in THF with excess EtMgBr, hydrolysis; extn. (ether), drying over Na2SO4; identification of individual compds.;

Reference yield: 70.0%

germanium(II) bis(3,5-di-tert-butyl-1,2-semiquinonate) (110577-18-9) + ethylmagnesium bromide (925-90-6) + germanium hydride trichloride (1184-65-2) → tetraethylgermane (597-63-7) + hexaethyldigermane (993-62-4) + octaethyltrigermane (13937-05-8)

Guidance literature:

With water; In benzene; heating reaction mixt. in C6H6 (tube fused, 48 h, 80°C), treatment with EtMgBr soln. (ether), hydrolysis; drying (Na2SO4), mixt. chromy.;

upstream raw materials:

Coppinger's Radikal

ethylmagnesium bromide

germanium hydride trichloride

pentaethyldigermane